Increase in the efficiency of proton phototransfer in a micellar solution by means of a base-carrier

Journal Article · Sat Feb 01 00:00:00 EST 1986 · Dokl. Phys. Chem. (Engl. Transl.); (United States)

OSTI ID:5187633

Zaitsev, A K; Il'chev, Y V; Kuz'min, M G; Zaitsev, N K

This paper focuses on the solution of attaining the maximum efficiency of proton phototransfer reactions and stabilizing the primary products of the photoreaction which are rich in energy. The authors investigated the protolytic reaction of 1-hydroxypyrene in CTAB micelles in the first singlet-excited state with the acetate anion. In the presence of the acetate anion in an aqueous micellar solution of CTAB, the efficiency of the protolytic reaction increases sharply. However, the value of the rate of the back reaction is close to the diffusion value.

• Research Organization: M.V. Lomonosov Moscow State Univ.
• OSTI ID: 5187633
• Journal Information: Dokl. Phys. Chem. (Engl. Transl.); (United States), Vol. 283:4-6
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
AMMONIUM HALIDES
PHOTOCHEMICAL REACTIONS
PROTONS
PYRENE
ACETATES
CHEMICAL REACTION KINETICS
ENERGY EFFICIENCY
FLUORESCENCE
HYDROGEN TRANSFER
MICELLAR SYSTEMS
ORGANIC BROMINE COMPOUNDS
PHOTOELECTROCHEMICAL CELLS
RHODOPSIN
SOLAR ENERGY CONVERSION
AMMONIUM COMPOUNDS
AROMATICS
BARYONS
CARBOXYLIC ACID SALTS
CHEMICAL REACTIONS
CONDENSED AROMATICS
CONVERSION
EFFICIENCY
ELECTROCHEMICAL CELLS
ELEMENTARY PARTICLES
ENERGY CONVERSION
EQUIPMENT
FERMIONS
HADRONS
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
KINETICS
LUMINESCENCE
NUCLEONS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
PIGMENTS
PROTEINS
REACTION KINETICS
SOLAR EQUIPMENT
400500* - Photochemistry