skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Continuous process of preparation of n-butyl(meth)acrylate by esterification of (meth)acrylic acid by butanol on thermostable sulfo-cation exchanger

Abstract

The authors propose an effective thermostable sulfo-cation exchanger based on polymers with a system of conjugated bonds, sulfopolyphenylene ketone (SPP) differing from the known cation exchangers by the high thermostability (up to 250/sup 0/C), and also having the effect of the stabilization of the double bond in unsaturated monomers. The combination of inhibiting and cation exchange properties makes it also possible to use these sulfo-cation exchangers in the processes of esterification of (meth)acrylic acids by alcohols without addition of special inhibitors. The SPP catalyst was tested in esterification processes of acrylic an methacrylic acid by butanol at a pilot plant.

Authors:
; ; ; ; ; ;
Publication Date:
Research Org.:
I. M. Gubkin Moscow Petroleum and Gas Institute (USSR)
OSTI Identifier:
5129373
Resource Type:
Journal Article
Journal Name:
J. Appl. Chem. USSR (Engl. Transl.); (United States)
Additional Journal Information:
Journal Volume: 60:5; Other Information: Translated from Zh. Prikl. Khim.; 60: No. 5, 1181-1182(May 1987)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ACRYLIC ACID ESTERS; SYNTHESIS; CATALYSTS; MATERIALS TESTING; KETONES; CATALYTIC EFFECTS; ION EXCHANGE; TEMPERATURE EFFECTS; METHACRYLIC ACID; ESTERIFICATION; ORGANIC ION EXCHANGERS; ACTIVATION ENERGY; BUTANOLS; ORGANIC SULFUR COMPOUNDS; POLYPHENYLS; STABILITY; ALCOHOLS; AROMATICS; CARBOXYLIC ACID ESTERS; CARBOXYLIC ACIDS; CHEMICAL REACTIONS; ENERGY; ESTERS; HYDROCARBONS; HYDROXY COMPOUNDS; ION EXCHANGE MATERIALS; MATERIALS; MONOCARBOXYLIC ACIDS; ORGANIC ACIDS; ORGANIC COMPOUNDS; TESTING; 400201* - Chemical & Physicochemical Properties

Citation Formats

Zheleznaya, L L, Karakhanov, R A, Lunin, A F, Magadov, R S, Meshcheryakov, S V, Mkrtychan, V R, and Fomin, V A. Continuous process of preparation of n-butyl(meth)acrylate by esterification of (meth)acrylic acid by butanol on thermostable sulfo-cation exchanger. United States: N. p., 1987. Web.
Zheleznaya, L L, Karakhanov, R A, Lunin, A F, Magadov, R S, Meshcheryakov, S V, Mkrtychan, V R, & Fomin, V A. Continuous process of preparation of n-butyl(meth)acrylate by esterification of (meth)acrylic acid by butanol on thermostable sulfo-cation exchanger. United States.
Zheleznaya, L L, Karakhanov, R A, Lunin, A F, Magadov, R S, Meshcheryakov, S V, Mkrtychan, V R, and Fomin, V A. 1987. "Continuous process of preparation of n-butyl(meth)acrylate by esterification of (meth)acrylic acid by butanol on thermostable sulfo-cation exchanger". United States.
@article{osti_5129373,
title = {Continuous process of preparation of n-butyl(meth)acrylate by esterification of (meth)acrylic acid by butanol on thermostable sulfo-cation exchanger},
author = {Zheleznaya, L L and Karakhanov, R A and Lunin, A F and Magadov, R S and Meshcheryakov, S V and Mkrtychan, V R and Fomin, V A},
abstractNote = {The authors propose an effective thermostable sulfo-cation exchanger based on polymers with a system of conjugated bonds, sulfopolyphenylene ketone (SPP) differing from the known cation exchangers by the high thermostability (up to 250/sup 0/C), and also having the effect of the stabilization of the double bond in unsaturated monomers. The combination of inhibiting and cation exchange properties makes it also possible to use these sulfo-cation exchangers in the processes of esterification of (meth)acrylic acids by alcohols without addition of special inhibitors. The SPP catalyst was tested in esterification processes of acrylic an methacrylic acid by butanol at a pilot plant.},
doi = {},
url = {https://www.osti.gov/biblio/5129373}, journal = {J. Appl. Chem. USSR (Engl. Transl.); (United States)},
number = ,
volume = 60:5,
place = {United States},
year = {Tue Nov 10 00:00:00 EST 1987},
month = {Tue Nov 10 00:00:00 EST 1987}
}