Synthesis of tris(triphenylsiloxy)yttrium and derivatives: Crystal structure of (Y(OSiPh sub 3 ) sub 3 (THF sub 3 ))ter dot THF
Journal Article
·
· Inorganic Chemistry; (USA)
- Indiaa Univ., Bloomington (USA)
The synthesis of (Y(OSiPh{sub 3}){sub 3}){sub n} (1) has been accomplished by the reaction of Y(N(SiMe{sub 3}){sub 2}){sub 3} with 3 equivalents of Ph{sub 3}SiOH in toluene. Two monomeric Lewis base adducts were also formed. The product 1 was formed as a colorless, feather-like solid, and {sup 1}H and {sup 13}C NMR spectra gave data consistent with the structure of this compound as an aggregate presumably involving bridging Ph{sub 3}SiO{sup {minus}} ligands. The x-ray structure of the compounds is also reported.
- OSTI ID:
- 5043409
- Journal Information:
- Inorganic Chemistry; (USA), Vol. 28:17; ISSN 0020-1669
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
AROMATICS
CHEMICAL PREPARATION
OXYGEN COMPOUNDS
SILICON COMPOUNDS
YTTRIUM COMPLEXES
CARBON 13
MOLECULAR STRUCTURE
NMR SPECTRA
PROTONS
BARYONS
CARBON ISOTOPES
COMPLEXES
ELEMENTARY PARTICLES
EVEN-ODD NUCLEI
FERMIONS
HADRONS
ISOTOPES
LIGHT NUCLEI
NUCLEI
NUCLEONS
ORGANIC COMPOUNDS
SPECTRA
STABLE ISOTOPES
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties
400202 - Isotope Effects
Isotope Exchange
& Isotope Separation
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
AROMATICS
CHEMICAL PREPARATION
OXYGEN COMPOUNDS
SILICON COMPOUNDS
YTTRIUM COMPLEXES
CARBON 13
MOLECULAR STRUCTURE
NMR SPECTRA
PROTONS
BARYONS
CARBON ISOTOPES
COMPLEXES
ELEMENTARY PARTICLES
EVEN-ODD NUCLEI
FERMIONS
HADRONS
ISOTOPES
LIGHT NUCLEI
NUCLEI
NUCLEONS
ORGANIC COMPOUNDS
SPECTRA
STABLE ISOTOPES
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties
400202 - Isotope Effects
Isotope Exchange
& Isotope Separation