[2 + 2] Cycloaddition of fullerenes with electron-rich alkenes and alkynes
Journal Article
·
· Journal of Organic Chemistry
- Univ. of California, Los Angeles, CA (United States)
[2+2] Cycloaddition between C{sub 60} and N,N-diethyl-4-methyl-3-penten-1-yn-1-amine (1) yields a C{sub 60}-fused cyclobutenamine under photochemical stimulation. Further photooxidation results in dihydrofullerenone amide. C{sub 60} and C{sub 70} react with tetraalkoxyethylenes to yield diketals which were unsuccessfully hydrolyzed. 68 refs., 1 fig.
- OSTI ID:
- 494163
- Journal Information:
- Journal of Organic Chemistry, Vol. 61, Issue 16; Other Information: PBD: 9 Aug 1996
- Country of Publication:
- United States
- Language:
- English
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