The first hexanuclear tungsten telluride clusters [W{sub 6}Te{sub 8}L{sub 6}]{sup n{minus}} as amine complexes with L = piperidine (n = 0) and L = pyridine (n = 1)
- Ames Lab., IA (United States)
The authors wished to examine the W{sub 6}Te{sub 8} complexes with the idea that the W{sub 6}Te{sub 8} binary compound might be more stable toward disproportionation than the W{sub 6}S{sub 8}{sup 6a} and W{sub 6}Se{sub 8} examples. In this paper, the authors report the synthesis and structures of the first two molecular telluride complexes with M{sub 6}Te{sub 8}{sup {minus}} and M{sub 6}Te{sub 8} (M = Mo, W) cluster cores.
- DOE Contract Number:
- W-7405-ENG-82
- OSTI ID:
- 486447
- Journal Information:
- Inorganic Chemistry, Vol. 35, Issue 10; Other Information: PBD: 8 May 1996
- Country of Publication:
- United States
- Language:
- English
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