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Title: Interstitially-stabilized praseodymium(III) compounds Na{sub 2}Pr{sub 4}Br{sub 9}NO and Pr{sub 8}Br{sub 13}N{sub 3}O: Structures on the border between salts and clusters

The authors describe the chemical preparation of the title compounds in sealed niobium tubing between 750 and 950 {degrees}C. Crystal structures of these compounds are reported. It is found that the structures bridge the gap between metal rich clusters and simple salts.
Authors:
; ;  [1]
  1. Iowa State Univ., Ames, IA (United States)
Publication Date:
OSTI Identifier:
458750
Resource Type:
Journal Article
Resource Relation:
Journal Name: Inorganic Chemistry; Journal Volume: 34; Journal Issue: 10; Other Information: PBD: 10 May 1995
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
40 CHEMISTRY; PRASEODYMIUM COMPOUNDS; CRYSTAL STRUCTURE; CHEMICAL PREPARATION