Synthesis of inorganic-organic hybrids from metal alkoxides and silanol-terminated polydimethylsiloxane
Book
·
OSTI ID:427711
- Nippon Steel Corp., Kawasaki, Kanagawa (Japan)
Inorganic-organic hybrids have been synthesized by reaction of Ti(OC{sub 2}H{sub 5}){sub 4} and Ta(OC{sub 2}H{sub 5}){sub 5} with silanol-terminated polydimethylsiloxane (PDMS). The chemical modification of the metal alkoxides with ethyl acetoacetate (EAcAc) was carried out in order to obtain a transparent and uniform hybrid. The hydrolysis behavior of Ti(OC{sub 2}H{sub 5}){sub 4} modified with EAcAc in the presence of PDMS and the formation of the Ti-O-Si bond in a Ti-O-PDMS hybrid were revealed by FT-IR experiments. Dynamic mechanical measurements showed that a Ta-O-PDMS hybrid was harder than a Ti-O-PDMS hybrid, indicating the effect of metal on the storage modulus of hybrids.
- OSTI ID:
- 427711
- Report Number(s):
- CONF-960401-; ISBN 1-55899-338-X; TRN: IM9708%%37
- Resource Relation:
- Conference: Spring meeting of the Materials Research Society (MRS), San Francisco, CA (United States), 8-12 Apr 1996; Other Information: PBD: 1996; Related Information: Is Part Of Better ceramics through chemistry 7: Organic/inorganic hybrid materials; Coltrain, B.K. [ed.] [Eastman Kodak Co., Rochester, NY (United States)]; Sanchez, C. [ed.] [Univ. Pierre et Marie Curie, Paris (France)]; Schaefer, D.W. [ed.] [Sandia National Labs., Albuquerque, NM (United States)]; Wilkes, G.L. [ed.] [Virginia Polytechnic Inst. and State Univ., Blacksburg, VA (United States)]; PB: 695 p.; Materials Research Society symposium proceedings, Volume 435
- Country of Publication:
- United States
- Language:
- English
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