Fingerprinting hydrocarbons in the biological resources of the Exxon Valdez spill area
- Exxon Production Research Co., Houston, TX (United States)
A procedure has been developed that discriminates Exxon Valdez crude from other sources of hydrocarbons found in Prince Williams Sound and the Gulf of Alaska. The procedure uses polycyclic aromatic hydrocarbon (PAH) distributions, measured by gas chromatography/mass spectrometry (GC/MS), to fingerprint sample extracts. The relative abundances of alkylated phenanthrenes, dibenzothiophenes, and chrysenes are used to differentiate Exxon Valdez crude and its weathering products from other hydrocarbons. Saturate fraction distributions are used to confirm the PAH identification whenever possible. The procedure has been applied to the more than 1,500 PAH analyses of tissues reported by the Oil Spill Health Task Force, formed after the spill to assess subsistence food safety, and nearly 4,700 PAH analyses of biological samples in PWSOIL, the government`s damage-assessment chemistry database. These two datasets constitute the largest collection of hydrocarbon analyses of biological samples form the spill-impact zone. 70 refs., 14 figs., 8 tabs.
- OSTI ID:
- 382755
- Report Number(s):
- CONF-930442-; ISBN 0-8031-1896-1; TRN: 96:025714
- Resource Relation:
- Conference: 3. symposium on environmental toxicology and risk assessment, Atlanta, GA (United States), 25-28 Apr 1993; Other Information: PBD: 1995; Related Information: Is Part Of Exxon Valdez oil spill: Fate and effects in Alaskan waters; Wells, P.G.; Butler, J.N.; Hughes, J.S. [eds.]; PB: 961 p.; ASTM special technical publication, 1219
- Country of Publication:
- United States
- Language:
- English
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