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Title: SELPhOx process for remediation of contaminated soil

Conference ·
OSTI ID:370591
 [1]; ;  [2];  [3]
  1. Univ. of Illinois, Chicago, IL (United States)
  2. Inst. of Gas Technology, Des Plaines, IL (United States)
  3. EPA National Risk Management Research Lab., Cincinnati, OH (United States)

The SELPhOx process is being developed as a highly flexible means of remediating and destroying both high and low concentrations of light aliphatic to heavy aromatic contaminants from solid and soil matrices. The process employs two distinct technologies: extraction of organic contaminants with supercritical carbon dioxide and wet air oxidation (WAO) destruction of the extracted contaminants. A separation step links the two process stages. IGT has conducted supercritical extraction tests over wide ranges of temperature, pressure, and CO{sub 2}/contaminant ratios with soils from a wood treatment plant and two manufacturing gas plant sites. The addition of methanol as an extraction modifier was also explored. At comparable CO{sub 2}-to-contaminant ratios and extraction conditions of 48{degrees}C and 137 atm, the total PAHs removed from the three soils ranged from 76.9 to 97.9 percent with CO{sub 2} alone and from 88.4 to 98.6 percent with methanol added. Results of these tests are presented.

OSTI ID:
370591
Report Number(s):
CONF-960376-; TRN: 96:003805-0647
Resource Relation:
Conference: Spring national meeting of the American Chemical Society (ACS), New Orleans, LA (United States), 24-28 Mar 1996; Other Information: PBD: 1996; Related Information: Is Part Of 211th ACS national meeting; PB: 2284 p.
Country of Publication:
United States
Language:
English