The kinetics of reactions of hexacarbonyls of chromium, molybdenum, and tungsten with hydroxylamine and trimethylamine oxide
Journal Article
·
· Russian Journal of Coordination Chemistry
OSTI ID:35658
- Institute of Inorganic Chemistry, Novosibirsk (Russian Federation)
The mechanism of the reactions of M(CO){sub 6}(M=Cr, Mo, and W) with hydroxylamine was studied. As follows from kinetic data, the reaction results in the oxidation of CO to CO{sub 2} and an intramolecular transfer of the formed amine to a central metal atom. The mechanisms of reactions of M(CO){sub 6} with hydroxylamine and trimethylamine oxide are compared.
- OSTI ID:
- 35658
- Journal Information:
- Russian Journal of Coordination Chemistry, Vol. 20, Issue 4; Other Information: PBD: Apr 1994; TN: Translated from Koordinatsionnaya Khimiya; 20: No. 4, 286-289(1994)
- Country of Publication:
- United States
- Language:
- English
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