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Title: Incineration of PCB-contaminated soils: Effect on soil properties

Conference ·
OSTI ID:287979
; ;  [1];  [2];  [3]
  1. Ecole Polytechnique, Montreal, Quebec (Canada). Chemical Engineering Dept.
  2. SNC Lavalin Inc., Montreal, Quebec (Canada)
  3. CINTEC Environnement Inc., Lasalle, Quebec (Canada)

An experimental program was conducted to determine the effect of fluidized bed combustion on the properties and characteristics of a soil lightly contaminated with PCBs. The following properties of a soil sample and its leachate were characterized before and after incineration: pH, particle size distribution, and contaminant content. Three runs were carried out on a pilot scale fluidized bed at identical conditions, with three different soil samples: set point temperature of 870 {+-} 40 C and minimal residence time of 30 min. The main conclusions can be summarized as follows: under the operating conditions of the test, PCBs present in soil are eliminated to below the detection level; the runs showed good reproducibility; soil pH increases from 8.6 {+-} 0.1 to 10.7 {+-} 0.2 because of the natural limestone (CaCO{sub 3}), which calcines and then hydrolyzes to basic calcium hydroxide (Ca(OH){sub 2}); the incineration seems to lead to soil agglomeration; soil heavy metal content is decreased significantly after incineration; soil leachate heavy metal content is not significantly affected by incineration, except for chromium (from 0.02 to 0.06 mg/L) and zinc (from 0.1 to 0.25 mg/L); treated soil leachate content for organics and organochlorines is below the detection level.

OSTI ID:
287979
Report Number(s):
CONF-950522-; ISBN 0-7918-1305-3; TRN: IM9639%%599
Resource Relation:
Conference: 13. international conference on fluidized-bed combustion, Orlando, FL (United States), 7-10 May 1995; Other Information: PBD: 1995; Related Information: Is Part Of 13. international conference on fluidized bed combustion: Proceedings. Volume 2; Heinschel, K.J. [ed.] [Air Products and Chemicals, Inc., Allentown, PA (United States)]; PB: 823 p.
Country of Publication:
United States
Language:
English