Free radical alkylation of titanium allyl complexes. Metal-mdeiated carbon-carbon bond formation in the odd-electron manifold
Conference
·
OSTI ID:250077
- Univ. of Alberta, Edmonton, Alberta (Canada)
Both nucleophilic and electrophilic addition to transition metal coordinated hydrocarbyl ligands has been extensively investigated, leading to the development of numerous synthetically important metal-mediated organic reactions. Free radical additions to coordinated ligands, however, remain rare and, in the organic context, virtually undeveloped. Here, the authors report the highly regioselective addition of organic free radicals to the central allyl carbon of paramagnetic titanocene(III) allyl complexes, providing an unusual, convenient, and general entry into the titanacyclobutane structural class.
- OSTI ID:
- 250077
- Report Number(s):
- CONF-9508100-; TRN: 96:002623-0015
- Resource Relation:
- Conference: 8. IUPAC symposium on organometallic chemistry directed towards organic synthesis, Santa Barbara, CA (United States), 6-10 Aug 1995; Other Information: PBD: 1995; Related Information: Is Part Of Eight IUPAC symposium on organometallic chemistry directed towards organic synthesis (OMCOS 8); PB: 375 p.
- Country of Publication:
- United States
- Language:
- English
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