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Title: Catalytic cracking of the top phase fraction of bio-oil into upgraded liquid oil

Journal Article · · AIP Conference Proceedings
DOI:https://doi.org/10.1063/1.4949315· OSTI ID:22608930
 [1]; ;  [2];  [3]
  1. Chemical Engineering Department, Riau University, Kampus Binawidya KM 12,5 Pekanbaru 28293 (Indonesia)
  2. Chemical Engineering Department, Gadjah Mada University, Jalan Grafika No. 2 Bulaksumur,Yogyakarta 55281 (Indonesia)
  3. Chemical Engineering Department, Gadjah Mada University, Jalan Grafika No. 2 Bulaksumur,Yogyakarta 55281(Indonesia)

The energy consumption is increasing, while oil reserves as a primary energy resource are decreasing, so that is the reason seeking alternative energy source is inevitable. Biomass especially oil palm empty fruit bunches (EFB) which is abundant in Indonesia can be processed into bio-oil by pyrolysis process. The potential for direct substitution of bio-oil for petroleum may be limited due to the high viscosity, high oxygen content, low heating value, and corrosiveness. Consequently, upgrading of the bio-oil before use is inevitable to give a wider variety of applications of its liquid product. Furthermore, upgrading process to improve the quality of bio-oil by reduction of oxygenates involves process such as catalytic cracking. The objective of this research is to study the effect of operation temperature on yield and composition of upgraded liquid oil and to determine physical properties. Bio-oil derived from EFB was upgraded through catalytic cracking using series tubular reactor under atmospheric pressure on a silica-alumina catalyst. Results show that increasing temperature from 450 to 600 °C, resulting in decreasing of upgraded liquid oil (ULO) yield, decreasing viscosity and density of ULO, but increasing in calorimetric value of ULO. The increasing temperature of cracking also will increase the concentration of gasoline and kerosene in ULO.

OSTI ID:
22608930
Journal Information:
AIP Conference Proceedings, Vol. 1737, Issue 1; Conference: 3. AUN/SEED-NET regional conference on energy engineering, Yogyakarta (Indonesia), 19-20 Nov 2015, RCENE/THERMOFLUID 2015: 7. international conference on thermofluids, Yogyakarta (Indonesia), 19-20 Nov 2015; Other Information: (c) 2016 Author(s); Country of input: International Atomic Energy Agency (IAEA); ISSN 0094-243X
Country of Publication:
United States
Language:
English