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Title: COMPREHENSIVE ANALYSIS OF PREBIOTIC PROPENAL UP TO 660 GHz

Since interstellar detection of propenal is only based on two rotational transitions in the centimeter wave region, its high resolution rotational spectrum has been measured up to 660 GHz and fully characterized by assignment of more than 12,000 transitions to provide direct laboratory data to the astronomical community. Spectral assignments and analysis include transitions from the ground state of the trans and cis isomers, three trans-{sup 13}C isotopologues, and ten excited vibrational states of the trans form. Combining new millimeter and submillimeter data with those from the far-infrared region has yielded the most precise set of spectroscopic constants of trans-propenal obtained to date. Newly determined rotational constants, centrifugal distortion constants, vibrational energies, and Coriolis and Fermi interaction constants are given with high accuracy and were used to predict transition frequencies and intensities over a wide frequency range. Results of this work should facilitate astronomers further observation of propenal in the interstellar medium.
Authors:
; ; ;  [1]
  1. Grupo de Espectroscopia Molecular (GEM), Edificio Quifima, Área de Química-Física, Laboratorios de Espectroscopia y Bioespectroscopia, Parque Científico UVa, Unidad Asociada CSIC, Universidad de Valladolid, E-47011 Valladolid (Spain)
Publication Date:
OSTI Identifier:
22520188
Resource Type:
Journal Article
Resource Relation:
Journal Name: Astrophysical Journal, Supplement Series; Journal Volume: 218; Journal Issue: 2; Other Information: Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
74 ATOMIC AND MOLECULAR PHYSICS; 79 ASTROPHYSICS, COSMOLOGY AND ASTRONOMY; ACROLEIN; CARBON 13; CORIOLIS FORCE; COSMIC GASES; DETECTION; FAR INFRARED RADIATION; FERMI INTERACTIONS; GHZ RANGE; GROUND STATES; INTERSTELLAR SPACE; ISOMERS; MOLECULES; RESOLUTION; VIBRATIONAL STATES