Morphology and conductivity study of solid electrolyte Li{sub 3}PO{sub 4}
Abstract
The comparison between two different methods of synthesize of solid electrolyte Li{sub 3}PO{sub 4} as precursor material for developing lithium ion battery, has been performed. The first method is to synthesize Li{sub 3}PO{sub 4} prepared by wet chemical reaction from LiOH and H{sub 3}PO{sub 4} which provide facile, abundant available resource, low cost, and low toxicity. The second method is solid state reaction prepared by Li{sub 2}CO{sub 3} and NH{sub 4}H{sub 2}PO{sub 4.} In addition, the possible morphology identification of comparison between two different methods will also be discussed. The composition, morphology, and additional identification phase and another compound of Li{sub 3}PO{sub 4} powder products from two different reaction are characterized by SEM, EDS, and EIS. The Li{sub 3}PO{sub 4} powder produced from wet reaction and solid state reaction have an average diameter of 0.834 – 7.81 µm and 2.15 – 17.3 µm, respectively. The density of Li{sub 3}PO{sub 4} prepared by wet chemical reaction is 2.238 gr/cm{sup 3}, little bit lower than the sample prepared by solid state reaction which density is 2.3560 gr/cm{sup 3}. The EIS measurement result shows that the conductivity of Li{sub 3}PO{sub 4} is 1.7 x 10{sup −9} S.cm{sup −1} for wet chemical reaction and 1.8 xmore »
- Authors:
-
- Engineering Physics, Sepuluh Nopember Institute of Technology ITS Campus, Sukolilo, Surabaya 6011 (Indonesia)
- Center for Science and Technology of Advanced Materials, National Nuclear Energy Agency Kawasan Puspiptek Serpong, Tangerang Selatan15314, Banten (Indonesia)
- Publication Date:
- OSTI Identifier:
- 22494623
- Resource Type:
- Journal Article
- Journal Name:
- AIP Conference Proceedings
- Additional Journal Information:
- Journal Volume: 1710; Journal Issue: 1; Conference: NNS2015: 6. nanoscience and nanotechnology symposium, Surakarta (Indonesia), 4-5 Nov 2015; Other Information: (c) 2016 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0094-243X
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; AMMONIUM PHOSPHATES; CHEMICAL REACTIONS; DENSITY; LITHIUM CARBONATES; LITHIUM HYDROXIDES; LITHIUM ION BATTERIES; LITHIUM PHOSPHATES; MORPHOLOGY; PHOSPHORIC ACID; POWDERS; PRECURSOR; SCANNING ELECTRON MICROSCOPY; SOLID ELECTROLYTES; SOLIDS; TOXICITY
Citation Formats
Prayogi, Lugas Dwi, E-mail: ldprayodi@gmail.com, Faisal, Muhamad, Kartini, Evvy, Honggowiranto, Wagiyo, and Supardi,. Morphology and conductivity study of solid electrolyte Li{sub 3}PO{sub 4}. United States: N. p., 2016.
Web. doi:10.1063/1.4941513.
Prayogi, Lugas Dwi, E-mail: ldprayodi@gmail.com, Faisal, Muhamad, Kartini, Evvy, Honggowiranto, Wagiyo, & Supardi,. Morphology and conductivity study of solid electrolyte Li{sub 3}PO{sub 4}. United States. https://doi.org/10.1063/1.4941513
Prayogi, Lugas Dwi, E-mail: ldprayodi@gmail.com, Faisal, Muhamad, Kartini, Evvy, Honggowiranto, Wagiyo, and Supardi,. 2016.
"Morphology and conductivity study of solid electrolyte Li{sub 3}PO{sub 4}". United States. https://doi.org/10.1063/1.4941513.
@article{osti_22494623,
title = {Morphology and conductivity study of solid electrolyte Li{sub 3}PO{sub 4}},
author = {Prayogi, Lugas Dwi, E-mail: ldprayodi@gmail.com and Faisal, Muhamad and Kartini, Evvy and Honggowiranto, Wagiyo and Supardi,},
abstractNote = {The comparison between two different methods of synthesize of solid electrolyte Li{sub 3}PO{sub 4} as precursor material for developing lithium ion battery, has been performed. The first method is to synthesize Li{sub 3}PO{sub 4} prepared by wet chemical reaction from LiOH and H{sub 3}PO{sub 4} which provide facile, abundant available resource, low cost, and low toxicity. The second method is solid state reaction prepared by Li{sub 2}CO{sub 3} and NH{sub 4}H{sub 2}PO{sub 4.} In addition, the possible morphology identification of comparison between two different methods will also be discussed. The composition, morphology, and additional identification phase and another compound of Li{sub 3}PO{sub 4} powder products from two different reaction are characterized by SEM, EDS, and EIS. The Li{sub 3}PO{sub 4} powder produced from wet reaction and solid state reaction have an average diameter of 0.834 – 7.81 µm and 2.15 – 17.3 µm, respectively. The density of Li{sub 3}PO{sub 4} prepared by wet chemical reaction is 2.238 gr/cm{sup 3}, little bit lower than the sample prepared by solid state reaction which density is 2.3560 gr/cm{sup 3}. The EIS measurement result shows that the conductivity of Li{sub 3}PO{sub 4} is 1.7 x 10{sup −9} S.cm{sup −1} for wet chemical reaction and 1.8 x 10{sup −10} S.cm{sup −1} for solid state reaction. The conductivity of Li{sub 3}PO{sub 4} is not quite different between those two samples even though they were prepared by different method of synthesize.},
doi = {10.1063/1.4941513},
url = {https://www.osti.gov/biblio/22494623},
journal = {AIP Conference Proceedings},
issn = {0094-243X},
number = 1,
volume = 1710,
place = {United States},
year = {Mon Feb 08 00:00:00 EST 2016},
month = {Mon Feb 08 00:00:00 EST 2016}
}