Synthesis and characterization of hydroxyapatite from fish bone waste

Journal Article · Tue Dec 29 00:00:00 EST 2015 · AIP Conference Proceedings

DOI:https://doi.org/10.1063/1.4938321· OSTI ID:22494467

Marliana, Ana; Fitriani, Eka; Ramadhan, Fauzan; Suhandono, Steven; Yuliani, Keti; Windarti, Tri ^[1]

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1. Chemistry Department, Faculty of Science and Mathematics, Diponegoro University, Indonesia, 50 275 (Indonesia)

Waste fish bones is a problem stemming from activities in the field of fisheries and it has not been used optimally. Fish bones contain calcium as natural source that used to synthesize hydroxyapatite (HA). In this research, HA synthesized from waste fish bones as local wisdom in Semarang. The goal are to produce HA with cheaper production costs and to reduce the environmental problems caused by waste bones. The novelty of this study was using of local fish bone as a source of calcium and simple method of synthesis. Synthesis process of HA can be done through a maceration process with firing temperatures of 1000°C or followed by a sol-gel method with firing at 550°C. The results are analyzed using FTIR (Fourier Transform Infrared), XRD (X-Ray Diffraction) and SEM-EDX (Scanning Electron Microscopy-Energy Dispersive X-Ray). FTIR spectra showed absorption of phosphate and OH group belonging to HA as evidenced by the results of XRD. The average grain size by maceration and synthesized results are not significant different, which is about 69 nm. The ratio of Ca/P of HA by maceration result is 0.89, then increase after continued in the sol-gel process to 1.41. Morphology of HA by maceration results are regular and uniform particle growth, while the morphology of HA after the sol-gel process are irregular and agglomerated.

• OSTI ID: 22494467
• Journal Information: AIP Conference Proceedings, Vol. 1699, Issue 1; Conference: International conference of chemical and material engineering (ICCME) 2015: Green technology for sustainable chemical products and processes, Semarang (Indonesia), 29-30 Sep 2015; Other Information: (c) 2015 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); ISSN 0094-243X
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
54 ENVIRONMENTAL SCIENCES
ABSORPTION
APATITES
CALCIUM
ENVIRONMENTAL IMPACTS
FISHERIES
FOURIER TRANSFORM SPECTROMETERS
GRAIN SIZE
INFRARED SPECTRA
MORPHOLOGY
PHOSPHATES
SCANNING ELECTRON MICROSCOPY
SKELETON
SOL-GEL PROCESS
SYNTHESIS
TEMPERATURE RANGE 0400-1000 K
TEMPERATURE RANGE 1000-4000 K
WASTE PRODUCT UTILIZATION
WASTES
X RADIATION
X-RAY DIFFRACTION