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Title: Y-doped La{sub 0.7}Ca{sub 0.3}MnO{sub 3} manganites exhibiting a large magnetocaloric effect and the crossover of first-order and second-order phase transitions

We prepared orthorhombic La{sub 0.7−x}Y{sub x}Ca{sub 0.3}MnO{sub 3} samples (x = 0, 0.04, 0.06, and 0.08) by conventional solid-state reaction and then studied their magnetic properties and magnetocaloric (MC) effect based on magnetization versus temperature and magnetic-field measurements, M(T, H). The experimental results revealed that an x increase in La{sub 0.7−x}Y{sub x}Ca{sub 0.3}MnO{sub 3} reduced the ferromagnetic-paramagnetic transition temperature (T{sub C}) from 260 K (for x = 0) to ∼126 K (for x = 0.08). Around the T{sub C}, maximum magnetic-entropy changes for a magnetic-field variation interval H = 50 kOe are about 10.7, 8.5, 7.4, and 5.8 J·kg{sup −1}·K{sup −1} for x = 0, 0.04, 0.06, and 0.08, respectively, corresponding to refrigerant capacities RC = 250–280 J·kg{sup −1}. These values are comparable to those of some conventional MC materials, revealing the applicability of La{sub 0.7−x}Y{sub x}Ca{sub 0.3}MnO{sub 3} in magnetic refrigeration. Using the Arrott method and scaling hypothesis as analyzing high-field M(H, T) data, and the universal-curve construction of the magnetic entropy change, we found a magnetic-phase separation. While the samples x = 0−0.06 exhibit a first-order magnetic phase transition, x = 0.08 exhibits the crossover of the first-to-second-order phase transformation (with its critical-exponent values close to those expected for the tricritical mean-field theory) and has the presence of ferromagnetic clusters even above the T{sub C}. Such the variationsmore » in the magnetism and MC effect are related to the changes in structural parameters caused by the Y substitution for La because Y doping does not change the concentration ratio of Mn{sup 3+}/Mn{sup 4+}.« less
Authors:
; ;  [1] ; ;  [2] ;  [3] ;  [4]
  1. Department of Physics and Oxide Research Center, Hankuk University of Foreign Studies, Yongin 449-791 (Korea, Republic of)
  2. Department of Physics, Chungbuk National University, Cheongju 361-763 (Korea, Republic of)
  3. Institute of Research and Development, Duy Tan University, Da Nang (Viet Nam)
  4. Institute of Materials Science, Vietnam Academy of Science and Technology, Hoang Quoc Viet, Cau Giay, Hanoi (Viet Nam)
Publication Date:
OSTI Identifier:
22492803
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Applied Physics; Journal Volume: 118; Journal Issue: 14; Other Information: (c) 2015 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; COMPARATIVE EVALUATIONS; DOPED MATERIALS; ENTROPY; MAGNETIC FIELDS; MAGNETIC PROPERTIES; MANGANESE IONS; MEAN-FIELD THEORY; ORTHORHOMBIC LATTICES; PARAMAGNETISM; PHASE TRANSFORMATIONS; REFRIGERANTS; REFRIGERATION; TRANSITION TEMPERATURE