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Title: Effect of pH of spray solution on the electrical properties of cadmium oxide thin films

Highly conducting transparent cadmium oxide thin films were prepared by conventional spray pyrolysis technique on glass at 375 °C substrate temperature. The pH of the spray solution was varied by adding ammonia/hydrochloric acid in the spray solution. The XRD pattern showed cubic phase. A lowest resistivity of 9.9 × 10{sup −4} Ω cm (with carrier concentration (n) = 5.1 × 10{sup 20} cm{sup −3}, mobility (µ)=12.4 cm{sup 2}/Vs) is observed for pH ∼12. The resistivity is tuned almost by three orders of magnitude by controlling the bath pH with optical transmittance more than 70 %. Thus, without any doping, the electrical conductivity of CdO films could be easily tuned by simply varying the pH of spray solution without compromising the transparency and keeping the other deposition parameters fixed.
Authors:
; ;  [1]
  1. Department of Physics, Karnatak University, Dharwad - 580 003, Karnataka (India)
Publication Date:
OSTI Identifier:
22490546
Resource Type:
Journal Article
Resource Relation:
Journal Name: AIP Conference Proceedings; Journal Volume: 1665; Journal Issue: 1; Conference: 59. DAE solid state physics symposium 2014, Tamilnadu (India), 16-20 Dec 2014; Other Information: (c) 2015 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; AMMONIA; CADMIUM OXIDES; CONCENTRATION RATIO; CUBIC LATTICES; DEPOSITION; ELECTRIC CONDUCTIVITY; GLASS; HYDROCHLORIC ACID; OPACITY; PH VALUE; PYROLYSIS; SOLUTIONS; SPRAYS; SUBSTRATES; THIN FILMS; X-RAY DIFFRACTION