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Title: Anisotropic superfluidity of {sup 4}He on a C{sub 36} fullerene molecule

We have performed path-integral Monte Carlo calculations to study the adsorption of {sup 4}He atoms on two different C{sub 36} isomers with the D{sub 6h} and the D{sub 2d} symmetries. The radial {sup 4}He density distributions reveal layer-by-layer growth with the first layer being located at a distance of ∼5.5 Å from the C{sub 36} molecular center and the second layer at ∼8.3 Å. From the angular density profiles of {sup 4}He, we find different quantum states as the number of {sup 4}He adatoms N varies. For N = 20, we observe commensurate solid structures on both D{sub 6h} and D{sub 2d} isomers, where each of 8 hexagon and 12 pentagon centers of the fullerene surfaces is occupied by a single {sup 4}He atom. The second-layer promotion starts beyond N = 38 on both isomers, where a compressible incommensurate structure is observed on the D{sub 6h} isomer and another commensurate structure on D{sub 2d}. Between N = 20 and N = 38, the {sup 4}He monolayer on D{sub 6h} shows several distinct rings of delocalized {sup 4}He atoms along with strongly anisotropic superfluid responses at low temperatures, while isotropic but weak superfluid responses are observed in the {sup 4}He layermore » on D{sub 2d}.« less
Authors:
; ;  [1]
  1. Division of Quantum Phases and Devices, School of Physics, Konkuk University, Seoul 143-701 (Korea, Republic of)
Publication Date:
OSTI Identifier:
22489573
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Chemical Physics; Journal Volume: 143; Journal Issue: 10; Other Information: (c) 2015 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ADSORPTION; ANISOTROPY; DENSITY; FULLERENES; HELIUM 4; ISOMERS; LAYERS; MOLECULES; MONTE CARLO METHOD; PATH INTEGRALS; QUANTUM STATES; SOLIDS; SUPERFLUIDITY; SURFACES