A novel second-order non-linear optical coordination polymer with three-fold interpenetrated CdSO{sub 4}-type network constructed by carboxylate–sulfonate ligands and strontium ions
Abstract
A novel strontium carboxylate–sulfonate coordination polymer, [Sr(HSIP)(H{sub 2}O){sub 3}]{sub n·}nH{sub 2}O (1) (NaH{sub 2}SIP=5-sulfoisophthalic monosodium salt) has been synthesized by hydrothermal reaction. It was characterized by X-ray single crystal diffraction, infrared spectroscopy, elemental and thermogravimetric analysis. Each strontium atom is eight-coordinate with a distorted bicapped trigonal prismatic arrangement. The whole HSIP{sup 2−} ligand acts as a η{sup 5}μ{sup 4} bridge to generate three-fold interpenetrated CdSO{sub 4}-type network structure, which is constructed from the left- and right-handed helixes paralleled to each other bridged by the HSIP{sup 2−} ligands. The luminescence spectrum indicates an emission maximum at 459 nm. Compound 1 shows a second harmonic generation (SHG) response that is 4 times that of KH{sub 2}PO{sub 4}. - Graphical abstract: The whole HSIP{sup 2−} ligands act as η{sup 5}μ{sup 4} bridges with strontium ions, and the strontium ion is eight-coordinated, showing a distorted bicapped trigonal prism geometry. - Highlights: • A novel coordination polymer with a CdSO{sub 4}-type network structure was synthesized. • It shows a second harmonic generation response that is 4 times that of KH{sub 2}PO{sub 4}. • It is constructed from the helixes paralleled to each other.
- Authors:
-
- School of Chemistry and Materials Science, Liaoning University of Petroleum and Chemical Engineering, Fushun 113001 (China)
- Center of Experiment, College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning University of Petroleum and Chemical Engineering, Fushun 113001 (China)
- Publication Date:
- OSTI Identifier:
- 22486813
- Resource Type:
- Journal Article
- Journal Name:
- Journal of Solid State Chemistry
- Additional Journal Information:
- Journal Volume: 230; Other Information: Copyright (c) 2015 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0022-4596
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ABSORPTION SPECTROSCOPY; CADMIUM SULFATES; CARBOXYLATION; HARMONIC GENERATION; HYDRATES; HYDROTHERMAL SYNTHESIS; INFRARED SPECTRA; LIGANDS; LUMINESCENCE; MONOCRYSTALS; POTASSIUM PHOSPHATES; SODIUM COMPOUNDS; SODIUM HYDRIDES; STRONTIUM IONS; SULFONATES; THERMAL GRAVIMETRIC ANALYSIS; X-RAY DIFFRACTION
Citation Formats
Guan, Lei, and Wang, Ying. A novel second-order non-linear optical coordination polymer with three-fold interpenetrated CdSO{sub 4}-type network constructed by carboxylate–sulfonate ligands and strontium ions. United States: N. p., 2015.
Web. doi:10.1016/J.JSSC.2015.07.008.
Guan, Lei, & Wang, Ying. A novel second-order non-linear optical coordination polymer with three-fold interpenetrated CdSO{sub 4}-type network constructed by carboxylate–sulfonate ligands and strontium ions. United States. https://doi.org/10.1016/J.JSSC.2015.07.008
Guan, Lei, and Wang, Ying. 2015.
"A novel second-order non-linear optical coordination polymer with three-fold interpenetrated CdSO{sub 4}-type network constructed by carboxylate–sulfonate ligands and strontium ions". United States. https://doi.org/10.1016/J.JSSC.2015.07.008.
@article{osti_22486813,
title = {A novel second-order non-linear optical coordination polymer with three-fold interpenetrated CdSO{sub 4}-type network constructed by carboxylate–sulfonate ligands and strontium ions},
author = {Guan, Lei and Wang, Ying},
abstractNote = {A novel strontium carboxylate–sulfonate coordination polymer, [Sr(HSIP)(H{sub 2}O){sub 3}]{sub n·}nH{sub 2}O (1) (NaH{sub 2}SIP=5-sulfoisophthalic monosodium salt) has been synthesized by hydrothermal reaction. It was characterized by X-ray single crystal diffraction, infrared spectroscopy, elemental and thermogravimetric analysis. Each strontium atom is eight-coordinate with a distorted bicapped trigonal prismatic arrangement. The whole HSIP{sup 2−} ligand acts as a η{sup 5}μ{sup 4} bridge to generate three-fold interpenetrated CdSO{sub 4}-type network structure, which is constructed from the left- and right-handed helixes paralleled to each other bridged by the HSIP{sup 2−} ligands. The luminescence spectrum indicates an emission maximum at 459 nm. Compound 1 shows a second harmonic generation (SHG) response that is 4 times that of KH{sub 2}PO{sub 4}. - Graphical abstract: The whole HSIP{sup 2−} ligands act as η{sup 5}μ{sup 4} bridges with strontium ions, and the strontium ion is eight-coordinated, showing a distorted bicapped trigonal prism geometry. - Highlights: • A novel coordination polymer with a CdSO{sub 4}-type network structure was synthesized. • It shows a second harmonic generation response that is 4 times that of KH{sub 2}PO{sub 4}. • It is constructed from the helixes paralleled to each other.},
doi = {10.1016/J.JSSC.2015.07.008},
url = {https://www.osti.gov/biblio/22486813},
journal = {Journal of Solid State Chemistry},
issn = {0022-4596},
number = ,
volume = 230,
place = {United States},
year = {Thu Oct 15 00:00:00 EDT 2015},
month = {Thu Oct 15 00:00:00 EDT 2015}
}