Role of the chemical substitution on the luminescence properties of solid solutions Ca{sub (1−x)}Cd{sub (x)}WO{sub 4} (0 ≤ x ≤1)

Taoufyq, A.; Mauroy, V.; Guinneton, F.; Bakiz, B.; Villain, S.; others, and

doi:10.1016/J.MATERRESBULL.2015.04.006

Title: Role of the chemical substitution on the luminescence properties of solid solutions Ca{sub (1−x)}Cd{sub (x)}WO{sub 4} (0 ≤ x ≤1)

Full Record
Other Related Research

Abstract

Highlights: • Luminescence can be modified by chemical substitution in solid solutions Ca{sub 1−x}Cd{sub x}WO{sub 4}. • The various emission spectra (charge transfer) were obtained under X-ray excitation. • Scheelite or wolframite solid solutions presented two types of emission spectra. • A luminescence component depended on cadmium substitution in each solid solution. • A component was only characteristic of oxyanion symmetry in each solid solution. - Abstract: We have investigated the chemical substitution effects on the luminescence properties under X-ray excitation of the solid solutions Ca{sub (1−x)}Cd{sub (x)}WO{sub 4} with 0 ≤ x ≤ 1. Two types of wide spectral bands, associated with scheelite-type or wolframite-type solid solutions, have been observed at room temperature. We decomposed each spectral band into several spectral components characterized by energies and intensities varying with composition x. One Gaussian component was characterized by an energy decreasing regularly with the composition x, while the other Gaussian component was only related to the tetrahedral or octahedral configurations of tungstate groups WO{sub 4}{sup 2−} or WO{sub 6}{sup 6−}. The luminescence intensities exhibited minimum values in the composition range x < 0.5 corresponding to scheelite-type structures, then, they regularly increased for cadmium compositions x > 0.5 corresponding to wolframite-typemore » structures.« less

Authors:

Taoufyq, A. ^[1]; Mauroy, V.; Guinneton, F. ^[1]; Bakiz, B. ^[2]; Villain, S. ^[1]; others, and

Institut Matériaux Microélectronique et Nanosciences de Provence, Aix Marseille Université, CNRS, Université de Toulon, IM2NP UMR 7334, 83957 La Garde (France)
Laboratoire Matériaux et Environnement LME, Faculté des Sciences, Université Ibn Zohr, BP 8106, Cité Dakhla, Agadir (Morocco)

Publication Date:: Thu Oct 15 00:00:00 EDT 2015

OSTI Identifier:: 22475887

Resource Type:: Journal Article

Journal Name:: Materials Research Bulletin

Additional Journal Information:: Journal Volume: 70; Other Information: Copyright (c) 2015 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0025-5408

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; CADMIUM COMPOUNDS; CALCIUM COMPOUNDS; CONFIGURATION; EMISSION SPECTRA; EXCITATION; LUMINESCENCE; SOLID SOLUTIONS; SYMMETRY; TEMPERATURE RANGE 0273-0400 K; TUNGSTATES; WOLFRAMITE; X RADIATION

Citation Formats


                    Taoufyq, A., Laboratoire Matériaux et Environnement LME, Faculté des Sciences, Université Ibn Zohr, BP 8106, Cité Dakhla, Agadir, CEA, DEN, Département d'Etudes des Réacteurs, Service de Physique Expérimentale, Laboratoire Dosimétrie Capteurs Instrumentation, 13108 Saint-Paul-lez-Durance, Mauroy, V., Guinneton, F., Bakiz, B., Villain, S., and others, and. Role of the chemical substitution on the luminescence properties of solid solutions Ca{sub (1−x)}Cd{sub (x)}WO{sub 4} (0 ≤ x ≤1).  United States: N. p., 2015. 
        Web.  doi:10.1016/J.MATERRESBULL.2015.04.006.

Copy to clipboard


                    Taoufyq, A., Laboratoire Matériaux et Environnement LME, Faculté des Sciences, Université Ibn Zohr, BP 8106, Cité Dakhla, Agadir, CEA, DEN, Département d'Etudes des Réacteurs, Service de Physique Expérimentale, Laboratoire Dosimétrie Capteurs Instrumentation, 13108 Saint-Paul-lez-Durance, Mauroy, V., Guinneton, F., Bakiz, B., Villain, S., & others, and. Role of the chemical substitution on the luminescence properties of solid solutions Ca{sub (1−x)}Cd{sub (x)}WO{sub 4} (0 ≤ x ≤1).  United States.  https://doi.org/10.1016/J.MATERRESBULL.2015.04.006

Copy to clipboard


                    Taoufyq, A., Laboratoire Matériaux et Environnement LME, Faculté des Sciences, Université Ibn Zohr, BP 8106, Cité Dakhla, Agadir, CEA, DEN, Département d'Etudes des Réacteurs, Service de Physique Expérimentale, Laboratoire Dosimétrie Capteurs Instrumentation, 13108 Saint-Paul-lez-Durance, Mauroy, V., Guinneton, F., Bakiz, B., Villain, S., and others, and. 2015.  
        "Role of the chemical substitution on the luminescence properties of solid solutions Ca{sub (1−x)}Cd{sub (x)}WO{sub 4} (0 ≤ x ≤1)".  United States.  https://doi.org/10.1016/J.MATERRESBULL.2015.04.006.

Copy to clipboard


                    
@article{osti_22475887,

  title        = {Role of the chemical substitution on the luminescence properties of solid solutions Ca{sub (1−x)}Cd{sub (x)}WO{sub 4} (0 ≤ x ≤1)},

  author       = {Taoufyq, A. and Laboratoire Matériaux et Environnement LME, Faculté des Sciences, Université Ibn Zohr, BP 8106, Cité Dakhla, Agadir and CEA, DEN, Département d'Etudes des Réacteurs, Service de Physique Expérimentale, Laboratoire Dosimétrie Capteurs Instrumentation, 13108 Saint-Paul-lez-Durance and Mauroy, V. and Guinneton, F. and Bakiz, B. and Villain, S. and others, and},

  abstractNote = {Highlights: • Luminescence can be modified by chemical substitution in solid solutions Ca{sub 1−x}Cd{sub x}WO{sub 4}. • The various emission spectra (charge transfer) were obtained under X-ray excitation. • Scheelite or wolframite solid solutions presented two types of emission spectra. • A luminescence component depended on cadmium substitution in each solid solution. • A component was only characteristic of oxyanion symmetry in each solid solution. - Abstract: We have investigated the chemical substitution effects on the luminescence properties under X-ray excitation of the solid solutions Ca{sub (1−x)}Cd{sub (x)}WO{sub 4} with 0 ≤ x ≤ 1. Two types of wide spectral bands, associated with scheelite-type or wolframite-type solid solutions, have been observed at room temperature. We decomposed each spectral band into several spectral components characterized by energies and intensities varying with composition x. One Gaussian component was characterized by an energy decreasing regularly with the composition x, while the other Gaussian component was only related to the tetrahedral or octahedral configurations of tungstate groups WO{sub 4}{sup 2−} or WO{sub 6}{sup 6−}. The luminescence intensities exhibited minimum values in the composition range x < 0.5 corresponding to scheelite-type structures, then, they regularly increased for cadmium compositions x > 0.5 corresponding to wolframite-type structures.},

  doi          = {10.1016/J.MATERRESBULL.2015.04.006},

  url          = {https://www.osti.gov/biblio/22475887},
  journal      = {Materials Research Bulletin},

  issn         = {0025-5408},

  number       = ,

  volume       = 70,

  place        = {United States},

  year         = {Thu Oct 15 00:00:00 EDT 2015},

  month        = {Thu Oct 15 00:00:00 EDT 2015}

}

Copy to clipboard

Journal Article:

https://doi.org/10.1016/J.MATERRESBULL.2015.04.006

Other availability

Find in Google Scholar

Search WorldCat to find libraries that may hold this journal

Save / Share:

Export Metadata

Save to My Library

Similar records in OSTI.GOV collections:

Structural, vibrational and luminescence properties of the (1−x)CaWO{sub 4}−xCdWO{sub 4} system

Journal Article Taoufyq, A.; Guinneton, F.; Valmalette, J-C.; ... - Journal of Solid State Chemistry

In the present work, we investigate the structural, microstructural, vibrational and luminescence properties of the system (1−x)CaWO{sub 4}−xCdWO{sub 4} with x ranging between 0 and 1. Polycrystalline samples were elaborated using a coprecipitation technique followed by thermal treatment at 1000 °C. The samples were then characterized using X-ray diffraction, scanning electron microscopy, Raman spectroscopy and luminescence analyses. X-ray diffraction profile analyses using Rietveld method showed that two kinds of solid solutions Ca{sub 1−x}Cd{sub x}WO{sub 4} having scheelite and wolframite structures, with respectively tetragonal and monoclinic crystal cells, were observed, with a biphasic system for compositions x=0.6 and 0.7. The scanningmore »« less
https://doi.org/10.1016/J.JSSC.2014.07.017
Influence of chemical substitution on the photoluminescence of Sr{sub (1−x)}Pb{sub x}WO{sub 4} solid solution

Journal Article Hallaoui, A.; Taoufyq, A.; Arab, M.; ... - Journal of Solid State Chemistry

The solid solution Sr{sub 1−x}Pb{sub x}WO{sub 4} based on luminescent tungstates SrWO{sub 4} and PbWO{sub 4} has been synthesized by solid-state reaction for all compositions 0≤x≤1. Using Rietveld method, the structural data of all polycrystalline samples have been refined and crystal cell parameters exhibited a linear behavior as a function of x. All substituted structures are of scheelite type. Scanning electron microscopy showed that a high level of crystallization characterized the samples, with modifications in sizes and shapes depending on composition x. Infrared and Raman spectroscopy have been performed to characterize the evolution of vibrational modes with substitution rate. Finally,more »« less
https://doi.org/10.1016/J.JSSC.2015.04.004
Successful synthesis of single scheelite-structured CdW{sub 1-x}Mo{sub x}O{sub 4} continuous solid-solution and its composition-dependent optoelectronic properties

Journal Article Wang, Yunjian; Wang, Junen; Geng, Lei; ... - Journal of Solid State Chemistry (Print)

Highlights: • Scheelite structure CdW{sub 1-x}Mo{sub x}O{sub 4} solid-solution was prepared for the first time. • Lattice expanded while band gap narrowed with the substitution of W{sup 6+} by Mo{sup 6+}. • Luminescent and dielectric properties of the solid solution varied with composition. - Abstract: Rational design and construction of metastable structured materials is more and more attractive toward realizing novel functional devices. In this work, the synthesis of metastable scheelite-type CdW{sub 1-x}Mo{sub x}O{sub 4} solid solution in the entire compositional range (0 ≤ x ≤ 1) was achieved for the first time. XRD, FT-IR and Raman spectroscopies confirmed thatmore »« less
https://doi.org/10.1016/J.JSSC.2018.07.011
Zn{sub 1−x}Co{sub x}WO{sub 4} (0 ≤ x ≤ 1) full range solid solution: Structure, optical properties, and magnetism

Journal Article Han, Shulei; Xiao, Ke; Liu, Liyuan; ... - Materials Research Bulletin

Graphical abstract: The continuous modulation on crystal structure and band gap is achieved in the Zn{sub 1−x}Co{sub x}WO{sub 4} (0 ≤ x ≤ 1) full range solid solution. - Highlights: • Zn{sub 1−x}Co{sub x}WO{sub 4} (0 ≤ x ≤ 1) solid solution was synthesized by a hydrothermal method. • They all present a single-phase in the wolframite structure with space group P2/c. • The continuous tenability in band gap was achieved in Zn{sub 1−x}Co{sub x}WO{sub 4} (0 ≤ x ≤ 1). • CoWO{sub 4} and Zn{sub 0.5}Co{sub 0.5}WO{sub 4} are antiferromagnetic and paramagnetic, respectively. - Abstract: A novel full-range solid-solutionmore »« less
https://doi.org/10.1016/J.MATERRESBULL.2015.10.026
Spectral and Structural Characteristics of (Lu{sub 1 –} {sub x}Eu{sub x}){sub 2}(WO{sub 4}){sub 3} Tungstates

Journal Article Kedrov, V.; Kiselev, A.; Fursova, T.; ... - Physics of the Solid State

The structure, luminescence, and IR absorption spectra of (Lu{sub 1 –} {sub x}Eu{sub x}){sub 2}(WO{sub 4}){sub 3} solid solutions are studied in a wide range of europium concentrations (0 ≤ x ≤ 1). As the europium concentration increases, two types of crystalline phases sequentially alternate. An orthorhombic phase (space group Pbcn) of tungstate solid solutions is observed at 0 ≤ x < 0.5. In the range 0.5 ≤ x ≤ 0.8, along with the orthorhombic phase, a monoclinic phase (space group C2/c) appears; at x > 0.8, the solid solution has a monoclinic structure. The correspondence between the structure and spectral characteristicsmore »« less
https://doi.org/10.1134/S1063783419110325

Similar Records