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Title: Structure, sintering behavior, and microwave dielectric properties of (1 − x) CaWO{sub 4}–xYLiF{sub 4} (0.02 ≤ x ≤ 0.10) ceramics

Highlights: • Structure, sinterability, and dielectric properties of CaWO{sub 4}–YLiF{sub 4} were studied. • CaWO{sub 4} can be densified (TD 97%) at 750 °C/2 h by YLiF{sub 4} doping. • Excellent microwave dielectric properties could be obtained. - Abstract: Structures and sintering behaviors of (1 − x) CaWO{sub 4}–xYLiF{sub 4} (0.02 ≤ x ≤ 0.10) ceramic have been investigated by X-ray powder diffraction (XRD), dilatometry, scanning electron microscopy (SEM) in this work. The microwave dielectric properties were measured with a network analyzer at the frequency of about 8–15 GHz. Limited solid solution could be formed within the compositional range of x < 0.1. The sintering temperature of CaWO{sub 4} could successfully be reduced to ∼750 °C/2 h by doping with small amount of YLiF{sub 4}. An optimized microwave dielectric properties with ϵ{sub r} = 10.5, Q × f = 73 000 GHz and τ{sub f} = −37.7 ppm/°C could be obtained after sintered at the 750 °C for 2 h for x = 0.04 compositions. XRD and back scattering SEM analysis indicated that the (1 − x) CaWO{sub 4}–xYLiF{sub 4} (x = 0.04) ceramic could be chemically compatible with Ag after sintering at 750 °C/2 h.
Authors:
;
Publication Date:
OSTI Identifier:
22475827
Resource Type:
Journal Article
Resource Relation:
Journal Name: Materials Research Bulletin; Journal Volume: 67; Other Information: Copyright (c) 2014 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; BACKSCATTERING; CALCIUM TUNGSTATES; CERAMICS; DIELECTRIC PROPERTIES; DILATOMETRY; LITHIUM FLUORIDES; MICROWAVE RADIATION; SCANNING ELECTRON MICROSCOPY; SINTERING; SOLID SOLUTIONS; X-RAY DIFFRACTION; YTTRIUM FLUORIDES