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Title: Top-grid monolayer graphene/Si Schottkey solar cell

Monolayer graphene/Si Schottkey solar cell was fabricated using a top-grid structure. In comparison with the prevailing “top-window” structure, the newly-designed device structure has simplified the fabrication procedures to avoid ultraviolet (UV) photolithography and SiO{sub 2}-eching. We systematically investigated the effect of chemical doping as well as device area on the device performance. It was found that a power conversion efficiency (PCE) of 5.9% can be achieved by engineering the work function of graphene through chemical doping. Our study indicates that top grid structure is suitable to make low-cost, large area and high efficiency graphene/Si Schottkey solar cell. - Graphical abstract: The engineering of the work function of graphene through chemical doping is an effective approach to improve the performance of monolayer graphene/Si Schottky solar cell. - Highlights: • Monolayer graphene/Si Schottkey solar cell was fabricated. • Chemical doping can effectively tune the work function of graphene film. • Chemical doping has significant effect on the device performance. • The top-grid device structure with graphene is promising with low-cost and high efficiency.
Authors:
; ;  [1] ;  [2] ; ;  [1] ;  [1] ;  [3]
  1. Institute of Functional Nano and Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, and Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou 215123 (China)
  2. Department of Materials Engineering, Monash University, Clayton 3800, VIC (Australia)
  3. (Australia)
Publication Date:
OSTI Identifier:
22475564
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Solid State Chemistry; Journal Volume: 224; Other Information: Copyright (c) 2014 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; COMPARATIVE EVALUATIONS; DESIGN; ENERGY EFFICIENCY; FABRICATION; FILMS; GRAPHENE; PHOTOVOLTAIC CONVERSION; SILICA; SILICON; SILICON OXIDES; SOLAR CELLS; ULTRAVIOLET RADIATION; WORK FUNCTIONS