skip to main content

SciTech ConnectSciTech Connect

Title: Synthesis and structure of spiro[2-(2-methylphenyl)-4H-1,3-benzoxazine-4,2′-adamantane]

Synthesis and an X-ray diffraction study of spiro[2-(2-methylphenyl)-4H-1,3-benzoxazine-4,2′-adamantane] C{sub 24}H{sub 25}NO are performed: monoclinic crystal system, space group P2{sub 1}/c, a = 13.9424(3) Å, b = 7.56554(17) Å, c = 17.0155(3) Å, β = 99.6457(18)°, Z = 4, V = 1769.45(6) Å{sup 3}. ρ{sub calcd} = 1.244 g/cm{sup 3}, R = 0.0339 [T = 100(2) K]. The oxazine ring of the molecule adopts the boat conformation. The bond lengths and angles are standard for this class of compounds.
Authors:
;  [1] ;  [2] ;  [1]
  1. Samara State Technical University (Russian Federation)
  2. Moscow State University, Faculty of Chemistry (Russian Federation)
Publication Date:
OSTI Identifier:
22472494
Resource Type:
Journal Article
Resource Relation:
Journal Name: Crystallography Reports; Journal Volume: 60; Journal Issue: 1; Other Information: Copyright (c) 2015 Pleiades Publishing, Inc.; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; BENZOXAZOLES; BOND ANGLE; BOND LENGTHS; CRYSTALS; CYCLOALKANES; MOLECULES; MONOCLINIC LATTICES; SYNTHESIS; X-RAY DIFFRACTION