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Title: Structure and thermal behavior of a nickel complex based on a V-shaped bis(4-(1H-imidazol-1-yl)phenyl)amine ligand

A new coordination polymer ([Ni(BIPA)(bpdc)(H{sub 2}O){sub 2}]){sub n} has been prepared based on a new V-shaped bis(4-(1H-imidazol-1-yl)phenyl)amine (BIPA) ligand. Complex was characterized by elemental analysis, IR spectra, X-ray powder diffraction, thermal analysis and single crystal X-ray analysis. Complex exhibits a 1D → 3D structure. Hydrogen bonds play an important role in the formation of supramolecular network structure. Thermal analysis indicates that complex exhibits a high thermal stability.
Authors:
; ; ; ;  [1]
  1. Nanjing University of Information Science & Technology, Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Innovative Research Laboratory of Energy & Environmental Catalysis, School of Environmental Science and Engineering (China)
Publication Date:
OSTI Identifier:
22472057
Resource Type:
Journal Article
Resource Relation:
Journal Name: Crystallography Reports; Journal Volume: 60; Journal Issue: 7; Other Information: Copyright (c) 2015 Pleiades Publishing, Inc.; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; AMINES; CHEMICAL BONDS; IMIDAZOLES; INFRARED SPECTRA; LIGANDS; MONOCRYSTALS; MULTI-ELEMENT ANALYSIS; NICKEL COMPLEXES; ORGANIC POLYMERS; PHASE STABILITY; PHASE STUDIES; THERMAL ANALYSIS; X-RAY DIFFRACTION