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Title: Synthesis and crystal structure of a novel Mn(II) coordination polymer with 3-(4-(1H-benzo[d]imidazol-1-yl)-4-methoxyphenyl)-1-phenylprop-2-en-1-one ligands

3-(4-(1H-Benzo[d]imidazol-1-yl)-4-methoxyphenyl)-1-phenylprop-2-en-1-one (L{sup 1}, 1) and its Mn(II) complex, [Mn(L{sup 1}){sub 2}(SCN){sub 2}]{sub ∞} (2), were synthesized and characterized by elemental analyses, IR spectroscopy and single-crystal X-ray diffraction. The Mn(II) ion in 2 is six-coordinated to four nitrogen atoms of two L{sup 1} ligands, two SCN-ligands, and two oxygen atoms of other two L{sup 1} ligands to form a distorted octahedral geometry. Therefore, each L{sup 1} links Mn ions through the O and N atoms to generate 2D sheet structure.
Authors:
 [1] ;  [2] ; ; ; ; ; ; ;  [1] ;  [3]
  1. Yuncheng University, Department of Applied Chemistry (China)
  2. Harbin Institute of Technology, Academy of Fundamental and Interdisciplinary Science (China)
  3. Jilin Medical College, College of Pharmacy (China)
Publication Date:
OSTI Identifier:
22472053
Resource Type:
Journal Article
Resource Relation:
Journal Name: Crystallography Reports; Journal Volume: 60; Journal Issue: 7; Other Information: Copyright (c) 2015 Pleiades Publishing, Inc.; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; ABSORPTION SPECTROSCOPY; CRYSTAL STRUCTURE; IMIDAZOLES; INFRARED SPECTRA; LIGANDS; MANGANESE COMPLEXES; MANGANESE IONS; MONOCRYSTALS; MULTI-ELEMENT ANALYSIS; NITROGEN; ORGANIC POLYMERS; OXYGEN; SYNTHESIS; X-RAY DIFFRACTION