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Title: Synthesis of new structurally related cyanamide compounds LiM(CN{sub 2}){sub 2} where M is Al{sup 3+}, In{sup 3+} or Yb{sup 3+}

Highlights: • New cyanamide compounds LiM(CN{sub 2}){sub 2} where M is Al{sup 3+}, In{sup 3+} or Yb{sup 3+}. • New luminescent material LiIn(CN{sub 2}){sub 2}:Tb{sup 3+}. • Reduction in efficiency of luminescence with temperature increase. - Abstract: New ternary cyanamide compounds isostructural to LiY(CN{sub 2}){sub 2} were obtained by solid state metathesis reaction. The crystal structure of LiAl(CN{sub 2}){sub 2} was determined by single crystal X-ray diffraction, the structures of LiIn(CN{sub 2}){sub 2} and LiYb(CN{sub 2}){sub 2} were solved from X-ray powder diffraction data. Photoluminescence properties of Tb{sup 3+}-doped LiIn(CN{sub 2}){sub 2} are reported too.
Authors:
 [1] ; ;  [1] ; ;  [2] ;  [1]
  1. Abteilung für Festkörperchemie und Theoretische Anorganische Chemie, Institut für Anorganische Chemie, Auf der Morgenstelle 18, Universität Tübingen, 72076 Tübingen (Germany)
  2. Fachhochschule Münster, Labor für Angewandte Materialwissenschaft, Stegerwaldstrasse 39, D-48565 Steinfurt (Germany)
Publication Date:
OSTI Identifier:
22420800
Resource Type:
Journal Article
Resource Relation:
Journal Name: Materials Research Bulletin; Journal Volume: 62; Other Information: Copyright (c) 2014 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; ALUMINIUM IONS; CARBON NITRIDES; CRYSTAL STRUCTURE; CYANIDES; DOPED MATERIALS; INDIUM IONS; LITHIUM COMPOUNDS; MONOCRYSTALS; PHOTOLUMINESCENCE; REDUCTION; SOLIDS; SYNTHESIS; TEMPERATURE DEPENDENCE; TERBIUM IONS; X-RAY DIFFRACTION; YTTERBIUM IONS