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Title: Measurement of anode surface temperature in carbon nanomaterial production by arc discharge method

Highlights: • We measured the temperature of anode surface by two-color pyrometry combined with a high speed camera successfully. • Growth temperature of pyrolytic graphite, MWNTs, and nano-graphite particles were in ranges of 2400–2600 K, 2600–2700 K, and 2700–3500 K, respectively. • High temperature contributes to form thermodynamically unstable material. - Abstract: Nano-graphite particles, multi-wall carbon nanotube (MWNT), and pyrolytic graphite were prepared at different positions of the anode surface in an arc discharge. Graphite electrodes were employed for the arc discharge under helium environment at atmospheric pressure. Nano-sized carbon products were characterized by scanning electron microscopy and transmission electron microscopy. During the arc discharge, two-color pyrometry combined with a high-speed camera was conducted to measure the temperature distribution of the anode surface. The growth temperature of pyrolytic graphite, MWNT, and nano-graphite particles were in the ranges of 2400–2600 K, 2600–2700 K, and 2700–3500 K, respectively. The local temperature of anode surface is a critical parameter to determine the products with different morphologies. The formation mechanism of these carbon nanomaterials is suggested based on the local temperature of anode surface and their thermodynamic stability.
Authors:
; ;  [1] ;  [1] ;  [2]
  1. Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, Yokohama 226-8502 (Japan)
  2. (Japan)
Publication Date:
OSTI Identifier:
22420663
Resource Type:
Journal Article
Resource Relation:
Journal Name: Materials Research Bulletin; Journal Volume: 60; Other Information: Copyright (c) 2014 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 77 NANOSCIENCE AND NANOTECHNOLOGY; ANODES; CARBON NANOTUBES; COLOR; GRAPHITE; MORPHOLOGY; NANOMATERIALS; NANOPARTICLES; PHASE STABILITY; SCANNING ELECTRON MICROSCOPY; SURFACES; TEMPERATURE DISTRIBUTION; TEMPERATURE MEASUREMENT; TRANSMISSION ELECTRON MICROSCOPY; VELOCITY