Mn-doped ZnFe{sub 2}O{sub 4} nanoparticles with enhanced performances as anode materials for lithium ion batteries

Journal Article · Mon Sep 15 00:00:00 EDT 2014 · Materials Research Bulletin

DOI:https://doi.org/10.1016/J.MATERRESBULL.2014.05.038· OSTI ID:22420552

Tang, Xiaoqin ^[1]; Hou, Xianhua ^[1]; Yao, Lingmin ^[1]; Hu, Shejun ^[1]; Liu, Xiang ^[2]; Xiang, Liangzhong ^[3]

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1. Laboratory of Quantum Engineering and Quantum Materials, School of Physics and Telecommunication Engineering, South China Normal University, Guangzhou 510006 (China)
2. Institute of Advanced Materials, Nanjing University of Technology, Nanjing 210009 (China)
3. Department of Radiation Physics, Stanford University, Arastradero, PA 1070 (United States)

Highlights: • Mn-doped ZnFe{sub 2}O{sub 4} nanoparticles have been synthesized by hydrothermal method. • Zn{sub 0.96}Mn{sub 0.04}Fe{sub 2}O{sub 4} electrode shows the highest reversible capacity of 1157 mA h g{sup −1}. • The Zn{sub 0.96}Mn{sub 0.04}Fe{sub 2}O{sub 4} electrode shows promising cycling stability. - Abstract: Nanocrystalline Zn{sub 1−x}Mn{sub x}Fe{sub 2}O{sub 4} (x = 0, 0.02, 0.04, 0.06, 0.08, 0.1) have been successfully synthesized by one-step hydrothermal method. The morphologies and electrochemical performance of Mn-doped ZnFe{sub 2}O{sub 4} in various proportions were investigated at room temperature, respectively. The Zn{sub 1−x}Mn{sub x}Fe{sub 2}O{sub 4} (x = 0.04) electrode in the as-synthesized samples showed the highest specific capacity of 1547 mA h g{sup −1} and 1157 mA h g{sup −1} in the initial discharge/charge process, with a coulombic efficiency of 74.8%. Additionally, excellent cycling stability was performed with a 1214 mA h g{sup −1} capacity retention at a current density of 100 mA g{sup −1} after 50 cycles. The corresponding mechanism was proposed which indicated that the Mn-doped ZnFe{sub 2}O{sub 4} nanoparticles experienced an aggregation thermochemical reaction among ZnO, MnO and Fe{sub 2}O{sub 3} subparticles.

• OSTI ID: 22420552
• Journal Information: Materials Research Bulletin, Vol. 57; Other Information: Copyright (c) 2014 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); ISSN 0025-5408
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
AGGLOMERATION
CRYSTALS
CURRENT DENSITY
DOPED MATERIALS
ELECTROCHEMISTRY
FERRITES
HYDROTHERMAL SYNTHESIS
IRON OXIDES
LITHIUM ION BATTERIES
LITHIUM IONS
MANGANESE OXIDES
MORPHOLOGY
NANOPARTICLES
NANOSTRUCTURES
PHASE STABILITY
TEMPERATURE RANGE 0273-0400 K
ZINC OXIDES