Electron impact ionization of cycloalkanes, aldehydes, and ketones
Abstract
The theoretical calculations of electron impact total ionization cross section for cycloalkane, aldehyde, and ketone group molecules are undertaken from ionization threshold to 2 keV. The present calculations are based on the spherical complex optical potential formalism and complex scattering potential ionization contribution method. The results of most of the targets studied compare fairly well with the recent measurements, wherever available and the cross sections for many targets are predicted for the first time. The correlation between the peak of ionization cross sections with number of target electrons and target parameters is also reported. It was found that the cross sections at their maximum depend linearly with the number of target electrons and with other target parameters, confirming the consistency of the values reported here.
- Authors:
-
- Department of Applied Physics, Indian School of Mines, Dhanbad, JH 826 004 (India)
- Publication Date:
- OSTI Identifier:
- 22419993
- Resource Type:
- Journal Article
- Journal Name:
- Journal of Chemical Physics
- Additional Journal Information:
- Journal Volume: 141; Journal Issue: 5; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0021-9606
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ALDEHYDES; COMPARATIVE EVALUATIONS; CROSS SECTIONS; CYCLOALKANES; ELECTRONS; IONIZATION; KETONES; KEV RANGE; MOLECULES; PEAKS; SCATTERING
Citation Formats
Gupta, Dhanoj, and Antony, Bobby. Electron impact ionization of cycloalkanes, aldehydes, and ketones. United States: N. p., 2014.
Web. doi:10.1063/1.4891472.
Gupta, Dhanoj, & Antony, Bobby. Electron impact ionization of cycloalkanes, aldehydes, and ketones. United States. https://doi.org/10.1063/1.4891472
Gupta, Dhanoj, and Antony, Bobby. 2014.
"Electron impact ionization of cycloalkanes, aldehydes, and ketones". United States. https://doi.org/10.1063/1.4891472.
@article{osti_22419993,
title = {Electron impact ionization of cycloalkanes, aldehydes, and ketones},
author = {Gupta, Dhanoj and Antony, Bobby},
abstractNote = {The theoretical calculations of electron impact total ionization cross section for cycloalkane, aldehyde, and ketone group molecules are undertaken from ionization threshold to 2 keV. The present calculations are based on the spherical complex optical potential formalism and complex scattering potential ionization contribution method. The results of most of the targets studied compare fairly well with the recent measurements, wherever available and the cross sections for many targets are predicted for the first time. The correlation between the peak of ionization cross sections with number of target electrons and target parameters is also reported. It was found that the cross sections at their maximum depend linearly with the number of target electrons and with other target parameters, confirming the consistency of the values reported here.},
doi = {10.1063/1.4891472},
url = {https://www.osti.gov/biblio/22419993},
journal = {Journal of Chemical Physics},
issn = {0021-9606},
number = 5,
volume = 141,
place = {United States},
year = {Thu Aug 07 00:00:00 EDT 2014},
month = {Thu Aug 07 00:00:00 EDT 2014}
}