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Title: Integral cross sections for electron impact excitation of vibrational and electronic states in phenol

We report on measurements of integral cross sections (ICSs) for electron impact excitation of a series of composite vibrational modes and electronic-states in phenol, where the energy range of those experiments was 15–250 eV. There are currently no other results against which we can directly compare those measured data. We also report results from our independent atom model with screened additivity rule correction computations, namely, for the inelastic ICS (all discrete electronic states and neutral dissociation) and the total ionisation ICS. In addition, for the relevant dipole-allowed excited electronic states, we also report f-scaled Born-level and energy-corrected and f-scaled Born-level (BEf-scaled) ICS. Where possible, our measured and calculated ICSs are compared against one another with the general level of accord between them being satisfactory to within the measurement uncertainties.
Authors:
 [1] ;  [2] ;  [2] ;  [1] ;  [3] ;  [4] ;  [5] ;  [6] ;  [1] ;  [7]
  1. School of Chemical and Physical Sciences, Flinders University, GPO Box 2100, Adelaide SA 5001 (Australia)
  2. (Brazil)
  3. Departamento de Física, Universidade Federal de Juiz de Fora, 36036-330 Juiz de Fora, Minas Gerais (Brazil)
  4. Departamento de Física Atómica, Molecular y Nuclear, Universidad Complutense de Madrid, 28040 Madrid (Spain)
  5. Instituto de Física Fundamental, CSIC, Serrano 113-bis, 28006 Madrid (Spain)
  6. Institute of Mathematical Sciences, University of Malaya, 50603 Kuala Lumpur (Malaysia)
  7. (Malaysia)
Publication Date:
OSTI Identifier:
22415799
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Chemical Physics; Journal Volume: 142; Journal Issue: 19; Other Information: (c) 2015 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ATOMS; CALCULATION METHODS; COMPARATIVE EVALUATIONS; CORRECTIONS; DIPOLES; DISSOCIATION; ELECTRON-MOLECULE COLLISIONS; ELECTRONS; EV RANGE; EXCITATION; INTEGRAL CROSS SECTIONS; PHENOL