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Title: Order within disorder: The atomic structure of ion-beam sputtered amorphous tantala (a-Ta{sub 2}O{sub 5})

Journal Article · · APL materials
DOI:https://doi.org/10.1063/1.4913586· OSTI ID:22415258
; ; ; ; ;  [1]; ;  [2]; ;  [3]; ;  [4]; ; ; ;  [5]
  1. E. L. Ginzton Laboratory, Stanford University, Stanford, California 94305 (United States)
  2. LIGO Laboratory, California Institute of Technology, Pasadena, California 91125 (United States)
  3. Department of Geological and Environmental Sciences, Stanford University, Stanford, California 94305 (United States)
  4. Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Menlo Park, California 94025 (United States)
  5. SUPA, School of Physics and Astronomy, University of Glasgow, Glasgow G12 8QQ (United Kingdom)

Amorphous tantala (a-Ta{sub 2}O{sub 5}) is a technologically important material often used in high-performance coatings. Understanding this material at the atomic level provides a way to further improve performance. This work details extended X-ray absorption fine structure measurements of a-Ta{sub 2}O{sub 5} coatings, where high-quality experimental data and theoretical fits have allowed a detailed interpretation of the nearest-neighbor distributions. It was found that the tantalum atom is surrounded by four shells of atoms in sequence; oxygen, tantalum, oxygen, and tantalum. A discussion is also included on how these models can be interpreted within the context of published crystalline Ta{sub 2}O{sub 5} and other a-T{sub 2}O{sub 5} studies.

OSTI ID:
22415258
Journal Information:
APL materials, Vol. 3, Issue 3; Other Information: (c) 2015 Author(s); Country of input: International Atomic Energy Agency (IAEA); ISSN 2166-532X
Country of Publication:
United States
Language:
English

Cited By (4)

Numerical study of the structural and vibrational properties of amorphous Ta 2 O 5 and TiO 2 -doped Ta 2 O 5 journal May 2016
Correlation between the transport mechanisms in conductive filaments inside Ta 2 O 5 -based resistive switching devices and in substoichiometric TaO x thin films journal May 2018
Investigation of effects of assisted ion bombardment on mechanical loss of sputtered tantala thin films for gravitational wave interferometers journal December 2019
Amorphous tantala and its relationship with the molten state journal April 2018