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Title: IUPAC-NIST Solubility Data Series. 100. Rare Earth Metal Fluorides in Water and Aqueous Systems. Part 2. Light Lanthanides (Ce–Eu)

This is the second part of the volume devoted to the evaluation of experimental solubility data for rare earth metal (REM) fluorides in water as well as in aqueous ternary and multicomponent systems. Fluorides of Ce, Pr, Nd, Pm, Sm, and Eu (so-called light lanthanides), as the main solutes, are covered in the present part, which has thorough coverage of the experimental literature through the end of 2012. The experimentally unknown solubility value for PmF{sub 3} in water was predicted by an interpolation of the solubility values for NdF{sub 3} and SmF{sub 3} at 298 K. General features of the systems, such as the nature of the equilibrium solid phases, solubility as a function of temperature, influence of ionic strength, pH, mixed solvent medium on the solubility, quality of the solubility results, and solubility as a function of REM atomic number, have already been presented in Part 1 of the volume.
Authors:
 [1] ;  [2] ;  [3]
  1. Institute of Nuclear Chemistry and Technology, Warsaw 03195 (Poland)
  2. Department of Chemistry, University of Warsaw, Warsaw 02093 (Poland)
  3. College of Chemistry and Chemical Engineering, Central South University, Changsha 410083 (China)
Publication Date:
OSTI Identifier:
22413361
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Physical and Chemical Reference Data; Journal Volume: 44; Journal Issue: 1; Other Information: (c) 2015 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; CERIUM; EQUILIBRIUM; EUROPIUM; INTERPOLATION; MIXED SOLVENTS; NEODYMIUM FLUORIDES; PH VALUE; SAMARIUM FLUORIDES; SOLIDS; SOLUBILITY; SOLUTES; TEMPERATURE DEPENDENCE; TEMPERATURE RANGE 0273-0400 K; VISIBLE RADIATION; WATER