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Title: Characterization of Cs vapor cell coated with octadecyltrichlorosilane using coherent population trapping spectroscopy

Journal Article · · Journal of Applied Physics
DOI:https://doi.org/10.1063/1.4919841· OSTI ID:22410186
; ; ; ; ;  [1]; ;  [2]
  1. FEMTO-ST, CNRS, UFC, 26 Chemin de l'Epitaphe, 25030 Besançon Cedex (France)
  2. LNE-SYRTE, Observatoire de Paris, CNRS, UPMC, 61 avenue de l'Observatoire, 75014 Paris (France)

We report the realization and characterization using coherent population trapping (CPT) spectroscopy of an octadecyltrichlorosilane (OTS)-coated centimeter-scale Cs vapor cell. The dual-structure of the resonance lineshape, with presence of a narrow structure line at the top of a Doppler-broadened structure, is clearly observed. The linewidth of the narrow resonance is compared to the linewidth of an evacuated Cs cell and of a buffer gas Cs cell of similar size. The Cs-OTS adsorption energy is measured to be (0.42 ± 0.03) eV, leading to a clock frequency shift rate of 2.7 × 10{sup −9}/K in fractional unit. A hyperfine population lifetime, T{sub 1}, and a microwave coherence lifetime, T{sub 2}, of 1.6 and 0.5 ms are reported, corresponding to about 37 and 12 useful bounces, respectively. Atomic-motion induced Ramsey narrowing of dark resonances is observed in Cs-OTS cells by reducing the optical beam diameter. Ramsey CPT fringes are detected using a pulsed CPT interrogation scheme. Potential applications of the Cs-OTS cell to the development of a vapor cell atomic clock are discussed.

OSTI ID:
22410186
Journal Information:
Journal of Applied Physics, Vol. 117, Issue 18; Other Information: (c) 2015 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); ISSN 0021-8979
Country of Publication:
United States
Language:
English