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Title: Giant magnetocaloric effect and temperature induced magnetization jump in GdCrO{sub 3} single crystal

We report on a systematic study of the single-crystal GdCrO{sub 3}, which shows various novel magnetic features, such as temperature-induced magnetization reversal (TMR), temperature-induced magnetization jump (TMJ), spin reorientation, and giant magnetocaloric effect (MCE). In the field-cooled cooling process with modest magnetic field along the c axis, GdCrO{sub 3} first shows a TMR at T{sub comp}∼120−130 K and then an abrupt TMJ with a sign change of magnetization at T{sub jump}∼52−120 K, and finally a spin reorientation at T{sub SR}∼4−7 K. Interestingly, the remarkable TMJ behavior, which was not reported ever before, persists at higher fields up to 10 kOe even when TMR disappears. In addition, giant MCE with the maximum value of magnetic entropy change reaching ∼31.6 J/kg K for a field change of 44 kOe was also observed in GdCrO{sub 3} single crystal, suggesting it could be a potential material for low-T magnetic refrigeration. A possible mechanism for these peculiar magnetic behaviors is discussed based on the various competing magnetic interactions between the 3d electrons of Cr{sup 3+} ions and 4f electrons of Gd{sup 3+} ions.
Authors:
; ; ; ;  [1] ;  [1] ;  [2] ;  [2]
  1. Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031 (China)
  2. (China)
Publication Date:
OSTI Identifier:
22399380
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Applied Physics; Journal Volume: 117; Journal Issue: 13; Other Information: (c) 2015 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; CHROMIUM IONS; CHROMIUM OXIDES; ELECTRONS; ENTROPY; EV RANGE; GADOLINIUM COMPOUNDS; GADOLINIUM IONS; MAGNETIC FIELDS; MAGNETIC PROPERTIES; MAGNETIZATION; MAGNETORESISTANCE; MONOCRYSTALS; SPIN; TEMPERATURE DEPENDENCE; TUNNEL EFFECT