Oxidation with the H{sub 2}O{sub 2}-VO{sub 3}{sup -} - pyrazine-2-carboxylic acid reagent 2. Oxidation of alcohols and aromatic hydrocarbons
Journal Article
·
· Russian Chemical Bulletin
OSTI ID:223932
- N.N. Semenov Inst. of Chemical Physics, Moscow (Russian Federation)
Aromatic hydrocarbons are oxidized with hydrogen peroxide in the presence of catalytic amounts of VO{sub 3}{sup -} and pyrazine-2-carboxylic acid into phenols (provided excess hydrocarbon is used) or into quinones (at high H{sub 2}O{sub 2} concentrations). 2-Propanol, ethanol, cyclohexanol, and benzyl alcohol are transformed into the corresponding aldehydes and ketones under the same conditions (without a solvent or in MeCN).
- OSTI ID:
- 223932
- Journal Information:
- Russian Chemical Bulletin, Vol. 42, Issue 8; Other Information: PBD: Feb 1994; TN: Translated from Izvestiya Akademii Nauk. Seriya Khimicheskaya; No. 8, 1394-1396(Aug 1993)
- Country of Publication:
- United States
- Language:
- English
Similar Records
Efficent H[sub 2]O[sub 2] oxidation of alkanes and arenes to alkyl peroxides and phenols catalyzed by the system vanadate-pyrazine-2-carboxylic acid
Mechanistic aspects of the higher alcohol synthesis over K[sub 2]O-promoted ZnCr oxide: Temperature-programmed reaction and flow experiments of C[sub 3], C[sub 4], and C[sub 5] oxygenates
Selective oxidation of primary alcohols to aldehydes by O/sub 2/ employing a trinuclear ruthenium carboxylate catalyst
Journal Article
·
Thu Jul 01 00:00:00 EDT 1993
· Journal of Catalysis; (United States)
·
OSTI ID:223932
Mechanistic aspects of the higher alcohol synthesis over K[sub 2]O-promoted ZnCr oxide: Temperature-programmed reaction and flow experiments of C[sub 3], C[sub 4], and C[sub 5] oxygenates
Journal Article
·
Mon Jun 01 00:00:00 EDT 1992
· Journal of Catalysis; (United States)
·
OSTI ID:223932
Selective oxidation of primary alcohols to aldehydes by O/sub 2/ employing a trinuclear ruthenium carboxylate catalyst
Journal Article
·
Wed Jun 10 00:00:00 EDT 1987
· J. Am. Chem. Soc.; (United States)
·
OSTI ID:223932