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Title: SPECTROSCOPIC CHARACTERIZATION AND DETECTION OF ETHYL MERCAPTAN IN ORION

New laboratory data of ethyl mercaptan, CH{sub 3}CH{sub 2}SH, in the millimeter- and submillimeter-wave domains (up to 880 GHz) provided very precise values of the spectroscopic constants that allowed the detection of gauche-CH{sub 3}CH{sub 2}SH toward Orion KL. This identification is supported by 77 unblended or slightly blended lines plus no missing transitions in the range 80-280 GHz. A detection of methyl mercaptan, CH{sub 3}SH, in the spectral survey of Orion KL is reported as well. Our column density results indicate that methyl mercaptan is ≅ 5 times more abundant than ethyl mercaptan in the hot core of Orion KL.
Authors:
; ;  [1] ; ;  [2] ; ;  [3]
  1. Grupo de Espectroscopía Molecular (GEM), Edificio Quifima, Laboratorios de Espectroscopía y Bioespectroscopía, Parque Científico UVa, Unidad Asociada CSIC, Universidad de Valladolid, E-47011 Valladolid (Spain)
  2. Departamento de Astrofísica, Centro de Astrobiología CAB, CSIC-INTA, Ctra. de Torrejón a Ajalvir km 4, E-28850 Madrid (Spain)
  3. Division of Natural Sciences, New College of Florida, Sarasota, FL 34243 (United States)
Publication Date:
OSTI Identifier:
22365963
Resource Type:
Journal Article
Resource Relation:
Journal Name: Astrophysical Journal Letters; Journal Volume: 784; Journal Issue: 1; Other Information: Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
79 ASTROPHYSICS, COSMOLOGY AND ASTRONOMY; ASTROPHYSICS; DENSITY; DETECTION; EMISSION SPECTROSCOPY; ENERGY-LEVEL TRANSITIONS; GHZ RANGE; MICROWAVE RADIATION; MOLECULES; STARS; THIOLS