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Title: BENZENE FORMATION ON INTERSTELLAR ICY MANTLES CONTAINING PROPARGYL ALCOHOL

Propargyl alcohol (CHCCH{sub 2}OH) is a known stable isomer of the propenal (CH{sub 2}CHCHO) molecule that was reported to be present in the interstellar medium (ISM). At astrochemical conditions in the laboratory, icy layers of propargyl alcohol grown at 85 K were irradiated by 2 keV electrons and probed by a Fourier Transform InfraRed spectrometer in the mid-infrared (IR) region, 4000-500 cm{sup –1}. Propargyl alcohol ice under astrochemical conditions was studied for the first time; therefore, IR spectra of reported amorphous (85 K) and crystalline (180 K) propargyl alcohol ices can be used to detect its presence in the ISM. Moreover, our experiments clearly show benzene (C{sub 6}H{sub 6}) formation to be the major product from propargyl alcohol irradiation, confirming the role of propargyl radicals (C{sub 3}H{sub 3}) formed from propargyl alcohol dissociation that was long expected based on theoretical modeling to effectively synthesize C{sub 6}H{sub 6} in the interstellar icy mantles.
Authors:
; ; ;  [1]
  1. Space and Atmospheric Sciences Division, Physical Research Laboratory, Ahmedabad (India)
Publication Date:
OSTI Identifier:
22364681
Resource Type:
Journal Article
Resource Relation:
Journal Name: Astrophysical Journal; Journal Volume: 798; Journal Issue: 2; Other Information: Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 79 ASTROPHYSICS, COSMOLOGY AND ASTRONOMY; ACROLEIN; ALCOHOLS; BENZENE; COMPUTERIZED SIMULATION; COSMOCHEMISTRY; DISSOCIATION; ELECTRONS; FOURIER TRANSFORMATION; INFRARED SPECTRA; INTERSTELLAR SPACE; IRRADIATION; ISOMERS; KEV RANGE; MOLECULES; PROPARGYL RADICALS