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Title: Thermal conductivity of vertically aligned carbon nanotube arrays: Growth conditions and tube inhomogeneity

Journal Article · · Applied Physics Letters
DOI:https://doi.org/10.1063/1.4898708· OSTI ID:22350893
; ; ;  [1]
  1. Department of Mechanical and Aerospace Engineering, University of Virginia, Charlottesville, Virginia 22904-4746 (United States)

The thermal conductivity of vertically aligned carbon nanotube arrays (VACNTAs) grown on silicon dioxide substrates via chemical vapor deposition is measured using a 3ω technique. For each sample, the VACNTA layer and substrate are pressed to a heating line at varying pressures to extract the sample's thermophysical properties. The nanotubes' structure is observed via transmission electron microscopy and Raman spectroscopy. The presence of hydrogen and water vapor in the fabrication process is tuned to observe the effect on measured thermal properties. The presence of iron catalyst particles within the individual nanotubes prevents the array from achieving the overall thermal conductivity anticipated based on reported measurements of individual nanotubes and the packing density.

OSTI ID:
22350893
Journal Information:
Applied Physics Letters, Vol. 105, Issue 15; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); ISSN 0003-6951
Country of Publication:
United States
Language:
English