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Title: Reversible modulated mid-infrared absorption of Ag/TiO{sub 2} by photoinduced interfacial charge transfer

Journal Article · · Applied Physics Letters
DOI:https://doi.org/10.1063/1.4898131· OSTI ID:22350849
; ; ;  [1]
  1. Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031 (China)

An enhanced mid-infrared absorption in Ag nanoparticles-decorated TiO{sub 2} microflowers was reported. It was found that the mid-infrared absorption of the Ag/TiO{sub 2} complex depends strongly on the content and size of Ag nanoparticles, the higher the Ag nanoparticles content, the stronger the infrared absorption. The average reflectivity in the entire mid-infrared region of the microflowers drops from 57.6% to 10.5% after Ag nanoparticles decoration. Reversible modulated mid-infrared absorption properties were found in the Ag/TiO{sub 2} complexes upon alternative illumination of visible and UV light due to the photoinduced interfacial electron transfer between TiO{sub 2} semiconductor and Ag nanoparticles.

OSTI ID:
22350849
Journal Information:
Applied Physics Letters, Vol. 105, Issue 14; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); ISSN 0003-6951
Country of Publication:
United States
Language:
English