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Title: Radiation damage and associated phase change effect on photodesorption rates from ices—Lyα studies of the surface behavior of CO{sub 2}(ice)

Photodesorption from a crystalline film of CO{sub 2}(ice) at 75 K has been studied using Lyα (10.2 eV) radiation. We combine quantitative mass spectrometric studies of gases evolved and transmission IR studies of species trapped in the ice. Direct CO desorption is observed from the primary CO{sub 2} photodissociation process, which occurs promptly for CO{sub 2} molecules located on the outermost surface of the ice (Process I). As the fluence of Lyα radiation increases to ∼5.5 × 10{sup 17} photons cm{sup –2}, extensive damage to the crystalline ice occurs and photo-produced CO molecules from deeper regions (Process II) are found to desorb at a rapidly increasing rate, which becomes two orders of magnitude greater than Process I. It is postulated that deep radiation damage to produce an extensive amorphous phase of CO{sub 2} occurs in the 50 nm ice film and that CO (and CO{sub 2}) diffusive transport is strongly enhanced in the amorphous phase. Photodesorption in Process II is a combination of electronic and thermally activated processes. Radiation damage in crystalline CO{sub 2} ice has been monitored by its effects on the vibrational line shapes of CO{sub 2}(ice). Here the crystalline-to-amorphous phase transition has been correlated with the occurrencemore » of efficient molecular transport over long distances through the amorphous phase of CO{sub 2}(ice). Future studies of the composition of the interstellar region, generated by photodesorption from ice layers on grains, will have to consider the significant effects of radiation damage on photodesorption rates.« less
Authors:
;  [1]
  1. Department of Chemistry, University of Virginia, Charlottesville, VA 22904 (United States)
Publication Date:
OSTI Identifier:
22348377
Resource Type:
Journal Article
Resource Relation:
Journal Name: Astrophysical Journal; Journal Volume: 780; Journal Issue: 1; Other Information: Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
79 ASTROPHYSICS, COSMOLOGY AND ASTRONOMY; AMORPHOUS STATE; CARBON DIOXIDE; CARBON MONOXIDE; COSMOLOGY; DESORPTION; DISSOCIATION; GALAXIES; ICE; LAYERS; MASS SPECTROSCOPY; MOLECULES; PHOTOLYSIS; PHOTONS; PHYSICAL RADIATION EFFECTS; STARS; TRANSMISSION; TRAPPING; ULTRAVIOLET RADIATION