Visible light activated photocatalytic behaviour of rare earth modified commercial TiO{sub 2}

Journal Article · Sat Feb 01 00:00:00 EST 2014 · Materials Research Bulletin

DOI:https://doi.org/10.1016/J.MATERRESBULL.2013.10.033· OSTI ID:22345211

Pullar, R. C. ^[1]; Škapin, A. Sever ^[2]; Seabra, M. P.; Labrincha, J. A. ^[1]

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1. Department of Materials and Ceramic Engineering/CICECO, University of Aveiro, Campus Universitário de Santiago, 3810-193 Aveiro (Portugal)
2. Slovenian National Building and Civil Engineering Institute, Dimičeva 12, SI-1000 Ljubljana (Slovenia)

Highlights: • RE gave more surface hydroxyl groups attached to the photocatalyst's surface. • RE gave the modified and fired samples a high specific surface area. • Photocatalytic activity was assessed in gas–solid phase under visible-light exposure. • Thermal treated RE-TiO{sub 2}s showed a superior visible-light photocatalytic activity. • La-TiO{sub 2} was the best performing photocatalyst. - Abstract: A commercial TiO{sub 2} nanopowder, Degussa P25, was modified with several rare earth (RE) elements in order to extend its photocatalytic activity into the visible range. The mixtures were prepared via solid-state reaction of the precursor oxides, and thermally treated at high temperature (900 and 1000 °C), with the aim of investigating the photocatalytic activity of the thermally treated samples. This thermal treatment was chosen for a prospective application as a surface layer in materials that need to be processed at high temperatures. The photocatalytic activity (PCA) of the samples was assessed in gas–solid phase – monitoring the degradation of isopropanol (IPA) – under visible-light irradiation. Results showed that the addition of the REs lanthanum, europium and yttrium to TiO{sub 2} greatly improved its photocatalytic activity, despite the thermal treatment, because of the presence of more surface hydroxyl groups attached to the photocatalyst's surface, together with a higher specific surface area (SSA) of the modified and thermally treated samples, with regard to the unmodified and thermally treated Degussa P25. The samples doped with La, Eu and Y all had excellent PCA under visible-light irradiation, even higher than the untreated Degussa P25 reference sample, despite their thermal treatment at 900 °C, with lanthanum producing the best results (i.e. the La-, Eu- and Y-TiO{sub 2} samples, thermally treated at 900 °C, had, respectively, a PCA equal to 26, 27 and 18 ppm h{sup −1} – in terms of acetone formation – versus 15 ppm h{sup −1} for the 900 °C thermally treated Degussa P25). On the other hand, Ce–TiO{sub 2}s had no significant photocatalytic activity.

• OSTI ID: 22345211
• Journal Information: Materials Research Bulletin, Vol. 50; Other Information: Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); ISSN 0025-5408
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
77 NANOSCIENCE AND NANOTECHNOLOGY
ACETONE
DOPED MATERIALS
EUROPIUM
HEAT TREATMENTS
HYDROXIDES
IRRADIATION
LANTHANUM
MIXTURES
NANOSTRUCTURES
OPTICAL PROPERTIES
PHASE TRANSFORMATIONS
PHOTOCATALYSIS
POWDERS
PROPANOLS
RAMAN SPECTROSCOPY
SOLIDS
SPECIFIC SURFACE AREA
TITANIUM OXIDES
YTTRIUM