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Title: The investigation of order–disorder transition process of ZSM-5 induced by spark plasma sintering

Based on the amorphization of zeolites, an order–disorder transition method was used to prepare silica glass via Spark Plasma Sintering (SPS). In order to get a better understanding about the mechanism of amorphization induced by SPS, the intermediate products in this process were prepared and characterized by different characterization techniques. X-ray diffraction and High-energy synchrotron X-ray scattering show a gradual transformation from ordered crystal to glass. Local structural changes in glass network including Si–O bond length, O–Si–O bond angle, size of rings, coordination were detected by Infrared spectroscopy and {sup 29}Si magic-angle spinning nuclear magnetic resonance (NMR) spectroscopy. Topologically ordered, amorphous material with a different intermediate-range structure can be obtained by precise control of intermediate process which can be expected to optimize and design material. - Graphical abstract: Low-density, ordered zeolites collapse to the rigid amorphous glass through spark plasma sintering. The intermediate-range structure formed in the process of order–disorder transition may give rise to specific property. - Highlights: • Order–disorder transition process of ZSM-5 induced by spark plasma sintering was investigated using several methods including XRD, High-energy synchrotron X-ray scattering, SAXS, IR, NMR, ect. • Order–disorder transition induced by SPS was compared with TIA and PIA. • Three stagesmore » has been divided during the whole process. • The collapse temperature range which may give rise to intermediate-range structure has been located.« less
Authors:
 [1] ;  [1] ;  [2] ;  [3]
  1. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, 2999 North Renmin Road, Songjiang, Shanghai 201620 (China)
  2. Engineering Research Center of Advanced Glasses Manufacturing Technology, MOE, Donghua University, 2999 North Renmin Road, Songjiang, Shanghai 201620 (China)
  3. Shanghai Institute of Applied Physics, Chinese Academy of Sciences, 239 Zhangheng Road, Pudong, Shanghai 200120 (China)
Publication Date:
OSTI Identifier:
22334173
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Solid State Chemistry; Journal Volume: 212; Other Information: Copyright (c) 2014 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ABSORPTION SPECTROSCOPY; BOND LENGTHS; CRYSTALS; INFRARED SPECTRA; NUCLEAR MAGNETIC RESONANCE; ORDER-DISORDER TRANSFORMATIONS; SILICA; SMALL ANGLE SCATTERING; X-RAY DIFFRACTION; ZEOLITES