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Title: Attenuation of wall disturbances in an electron cyclotron resonance oxygen–argon plasma using real time control

Abstract

Present practice in plasma-assisted semiconductor manufacturing specifies recipes in terms of inputs such as gas flow rates, power and pressure. However, ostensibly identical chambers running identical recipes may produce very different results. Extensive chamber matching, i.e., initial iterative, empirical tuning of the process recipe, which entails time-consuming, ex situ statistical analysis of process metrics such as etch depth, uniformity, anisotropy and selectivity, is required to ensure acceptable results. Once matched, chambers are run open loop and are thus sensitive to disturbances such as actuator drift, wall seasoning and substrate loading, which may impact negatively on process reproducibility. An alternative approach, which may obviate the need for chamber matching and reduce the sensitivity of process metrics to exogenous disturbances, would be to specify a recipe in terms of quantities such as active species densities, and to regulate these in real time by adjusting the inputs with a suitable control algorithm. In this work, real time control of an electron cyclotron resonance O{sub 2}/Ar plasma used for photoresist ashing has been implemented. The design of elementary, model-based algorithms for the control of the argon 750 and oxygen 844 line intensities measured by optical emission spectroscopy is described. Fluorination of the chamber wallsmore » by means of an SF{sub 6} plasma prior to ashing inhibits wall recombination of oxygen radicals resulting in an approximately 20% increase in ash rate in the open loop case. However, closed loop control almost completely attenuates the effect of fluorination, thus demonstrating the efficacy of the control algorithms in ensuring a reproducible ash rate in the face of a wall disturbance.« less

Authors:
; ;  [1]; ;  [2];  [3]
  1. National Centre for Plasma Science and Technology (NCPST), Research and Engineering Building, Dublin City University, Glasnevin, Dublin 9, Ireland and School of Physical Sciences, Dublin City University, Glasnevin, Dublin 9 (Ireland)
  2. National Centre for Plasma Science and Technology (NCPST), Research and Engineering Building, Dublin City University, Glasnevin, Dublin 9, Ireland and School of Electronic Engineering, Dublin City University, Glasnevin, Dublin 9 (Ireland)
  3. School of Electronic Engineering, Dublin City University, Glasnevin, Dublin 9 (Ireland)
Publication Date:
OSTI Identifier:
22318070
Resource Type:
Journal Article
Journal Name:
Journal of Vacuum Science and Technology. A, Vacuum, Surfaces and Films
Additional Journal Information:
Journal Volume: 32; Journal Issue: 4; Other Information: (c) 2014 American Vacuum Society; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0734-2101
Country of Publication:
United States
Language:
English
Subject:
71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; 42 ENGINEERING; ALGORITHMS; ARGON; CLOSED-LOOP CONTROL; DISTURBANCES; ELECTRON CYCLOTRON-RESONANCE; EMISSION SPECTROSCOPY; FLUORINATION; GAS FLOW; OXYGEN; PLASMA; SEMICONDUCTOR MATERIALS; SULFUR FLUORIDES

Citation Formats

Keville, Bernard, Gaman, Cezar, Turner, Miles M., Zhang, Yang, Daniels, Stephen, and Holohan, Anthony M. Attenuation of wall disturbances in an electron cyclotron resonance oxygen–argon plasma using real time control. United States: N. p., 2014. Web. doi:10.1116/1.4879458.
Keville, Bernard, Gaman, Cezar, Turner, Miles M., Zhang, Yang, Daniels, Stephen, & Holohan, Anthony M. Attenuation of wall disturbances in an electron cyclotron resonance oxygen–argon plasma using real time control. United States. https://doi.org/10.1116/1.4879458
Keville, Bernard, Gaman, Cezar, Turner, Miles M., Zhang, Yang, Daniels, Stephen, and Holohan, Anthony M. 2014. "Attenuation of wall disturbances in an electron cyclotron resonance oxygen–argon plasma using real time control". United States. https://doi.org/10.1116/1.4879458.
@article{osti_22318070,
title = {Attenuation of wall disturbances in an electron cyclotron resonance oxygen–argon plasma using real time control},
author = {Keville, Bernard and Gaman, Cezar and Turner, Miles M. and Zhang, Yang and Daniels, Stephen and Holohan, Anthony M.},
abstractNote = {Present practice in plasma-assisted semiconductor manufacturing specifies recipes in terms of inputs such as gas flow rates, power and pressure. However, ostensibly identical chambers running identical recipes may produce very different results. Extensive chamber matching, i.e., initial iterative, empirical tuning of the process recipe, which entails time-consuming, ex situ statistical analysis of process metrics such as etch depth, uniformity, anisotropy and selectivity, is required to ensure acceptable results. Once matched, chambers are run open loop and are thus sensitive to disturbances such as actuator drift, wall seasoning and substrate loading, which may impact negatively on process reproducibility. An alternative approach, which may obviate the need for chamber matching and reduce the sensitivity of process metrics to exogenous disturbances, would be to specify a recipe in terms of quantities such as active species densities, and to regulate these in real time by adjusting the inputs with a suitable control algorithm. In this work, real time control of an electron cyclotron resonance O{sub 2}/Ar plasma used for photoresist ashing has been implemented. The design of elementary, model-based algorithms for the control of the argon 750 and oxygen 844 line intensities measured by optical emission spectroscopy is described. Fluorination of the chamber walls by means of an SF{sub 6} plasma prior to ashing inhibits wall recombination of oxygen radicals resulting in an approximately 20% increase in ash rate in the open loop case. However, closed loop control almost completely attenuates the effect of fluorination, thus demonstrating the efficacy of the control algorithms in ensuring a reproducible ash rate in the face of a wall disturbance.},
doi = {10.1116/1.4879458},
url = {https://www.osti.gov/biblio/22318070}, journal = {Journal of Vacuum Science and Technology. A, Vacuum, Surfaces and Films},
issn = {0734-2101},
number = 4,
volume = 32,
place = {United States},
year = {Tue Jul 01 00:00:00 EDT 2014},
month = {Tue Jul 01 00:00:00 EDT 2014}
}