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Title: Origin of electrons emitted into vacuum from InGaN light emitting diodes

Journal Article · · Applied Physics Letters
DOI:https://doi.org/10.1063/1.4892473· OSTI ID:22314487
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  1. Materials Department, University of California, Santa Barbara, California 93106-5050 (United States)
  2. Laboratoire de Physique de la Matière Condensée, CNRS-Ecole Polytechnique, 91128 Palaiseau Cedex (France)
  3. Seoul Viosys Co., Ltd., 1-36 727, Won-Si Dong, Danwon-Gu, Ansan City, Kyunggi-do 425-851 (Korea, Republic of)

The mechanism responsible for efficiency droop in InGaN light-emitting diodes (LEDs) has long been elusive due to indirect measurement techniques used for its identification. Auger recombination is unique among proposed efficiency droop mechanisms, in that it is the only mechanism capable of generating hot carriers. In a previous study [J. Iveland et al., Phys. Rev. Lett. 110, 177406 (2013)], we performed electron energy analysis of electrons emitted into vacuum from a forward biased InGaN LED that had been brought into negative electron affinity by cesiation. Three peaks were observed in the energy spectrum of vacuum emitted electrons. In this Letter, we unambiguously identify the origin of the peaks. The two higher energy peaks correspond to accumulation of electrons transported to the surface in the bulk Γ and side L conduction band valleys. The L-valley peak is a direct signature of a hot Auger electron population. The lower energy peak results from surface photoemission induced by the internal LED light emitted from the InGaN quantum wells. Two control experiments were performed. In the first, a simple GaN pn junction generated only a single Γ peak in electroemission. In the second, selective detection of the photoemission from an LED under modulated light excitation and DC electrical injection confirms that only the low energy peak is photogenerated and that LED light is incapable of generating Γ or L-valley peaks, the latter only occurring due to the Auger effect in the LED active region.

OSTI ID:
22314487
Journal Information:
Applied Physics Letters, Vol. 105, Issue 5; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); ISSN 0003-6951
Country of Publication:
United States
Language:
English

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Temperature-dependent efficiency droop of blue InGaN micro-light emitting diodes journal October 2014
Looking for Auger signatures in III-nitride light emitters: A full-band Monte Carlo perspective journal February 2015
Identification of low-energy peaks in electron emission spectroscopy of InGaN/GaN light-emitting diodes journal August 2018
Recombination dynamics in GaInN/GaN quantum wells journal June 2019
Direct measurement of hot-carrier generation in a semiconductor barrier heterostructure: Identification of the dominant mechanism for thermal droop journal September 2019
High wall-plug efficiency blue III-nitride LEDs designed for low current density operation journal January 2017
A Review on Experimental Measurements for Understanding Efficiency Droop in InGaN-Based Light-Emitting Diodes journal October 2017