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Title: Monovalent metal phenylphosphonates and phenylarsonates: Single crystal X-ray structures of A(HO{sub 3}PPh)(H{sub 2}O{sub 3}PPh) (A = K, Rb, Cs, Tl) and Na(HO{sub 3}AsPh)(H{sub 2}O{sub 3}AsPh) and methylamine intercalation of A(HO{sub 3}PPh)(H{sub 2}O{sub 3}PPh) (A = Li, Na, K, Tl)

Single crystal X-ray structures of known A(HO{sub 3}PPh)(H{sub 2}O{sub 3}PPh) (A = K, Rb, Cs, Tl) phenylphosphonates and sodium phenylarsonate, Na(HO{sub 3}AsPh)(H{sub 2}O{sub 3}AsPh) have been determined. This and previous studies together describe the four types of structures of a series of seven A(HO{sub 3}PPh)(H{sub 2}O{sub 3}PPh) (A = Li, Na, K, Rb, Cs, Tl, NH{sub 4}) phenylphosphonates. Sodium phenylarsonate is isostructural with its phenylphosphonate analogue. A(HO{sub 3}PPh)(H{sub 2}O{sub 3}PPh) (A = Li, Na, K and Tl) compounds undergo methylamine intercalation. - Graphical abstract: Amongst A(HO{sub 3}PPh)(H{sub 2}O{sub 3}PPh) (A = alkali metal, Tl) phenylphosphonates of four structure types, lithium, sodium, potassium and thallium compounds undergo methylamine intercalation. - Highlights: • X-ray structures of A(HO{sub 3}PPh)(H{sub 2}O{sub 3}PPh) (A = K, Rb, Cs, Tl) and Na(HO{sub 3}AsPh)(H{sub 2}O{sub 3}AsPh). • Four structure types of seven A(HO{sub 3}PPh)(H{sub 2}O{sub 3}PPh) (A = monovalent ion) compounds. • Methylamine intercalation of A(HO{sub 3}PPh)(H{sub 2}O{sub 3}PPh) (A = Li, Na, K, Tl) compounds.
Authors:
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Publication Date:
OSTI Identifier:
22309053
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Solid State Chemistry; Journal Volume: 203; Other Information: Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CRYSTAL STRUCTURE; IONS; LITHIUM; METHYLAMINE; MONOCRYSTALS; POTASSIUM; SODIUM; X RADIATION