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Title: Direct synthesis of BiCuChO-type oxychalcogenides by mechanical alloying

Abstract

We report on the direct synthesis of BiCuChO based materials by mechanical alloying (Ch=Se, Te). We show that contrary to the synthesis paths used in the previous reports dealing with this family of materials, which use costly annealings in closed silica tubes under controlled atmosphere, this new synthesis route enables the synthesis of pure phase materials at room temperature under air, with reasonable milling time. This synthesis procedure is easily scalable for large scale applications. - Highlights: • Phase pure BiCuSeO doped and undoped prepared by mechanical alloying. • Synthesis performed under air at room temperature. • Electrical properties similar to that of samples synthesized by a classical path.

Authors:
;  [1];  [2];  [1];  [2]; ;  [1];  [2]
  1. Institut de Chimie Moléculaire et des Matériaux d’Orsay, Univ. Paris-Sud, UMR 8182, Orsay F-91405 (France)
  2. France
Publication Date:
OSTI Identifier:
22309035
Resource Type:
Journal Article
Journal Name:
Journal of Solid State Chemistry
Additional Journal Information:
Journal Volume: 203; Other Information: Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0022-4596
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ANNEALING; CONTROLLED ATMOSPHERES; DOPED MATERIALS; ELECTRICAL PROPERTIES; SILICA; SYNTHESIS

Citation Formats

Pele, Vincent, Barreteau, Celine, CNRS, Orsay F-91405, Berardan, David, CNRS, Orsay F-91405, Zhao, Lidong, Dragoe, Nita, and CNRS, Orsay F-91405. Direct synthesis of BiCuChO-type oxychalcogenides by mechanical alloying. United States: N. p., 2013. Web. doi:10.1016/J.JSSC.2013.04.029.
Pele, Vincent, Barreteau, Celine, CNRS, Orsay F-91405, Berardan, David, CNRS, Orsay F-91405, Zhao, Lidong, Dragoe, Nita, & CNRS, Orsay F-91405. Direct synthesis of BiCuChO-type oxychalcogenides by mechanical alloying. United States. https://doi.org/10.1016/J.JSSC.2013.04.029
Pele, Vincent, Barreteau, Celine, CNRS, Orsay F-91405, Berardan, David, CNRS, Orsay F-91405, Zhao, Lidong, Dragoe, Nita, and CNRS, Orsay F-91405. 2013. "Direct synthesis of BiCuChO-type oxychalcogenides by mechanical alloying". United States. https://doi.org/10.1016/J.JSSC.2013.04.029.
@article{osti_22309035,
title = {Direct synthesis of BiCuChO-type oxychalcogenides by mechanical alloying},
author = {Pele, Vincent and Barreteau, Celine and CNRS, Orsay F-91405 and Berardan, David and CNRS, Orsay F-91405 and Zhao, Lidong and Dragoe, Nita and CNRS, Orsay F-91405},
abstractNote = {We report on the direct synthesis of BiCuChO based materials by mechanical alloying (Ch=Se, Te). We show that contrary to the synthesis paths used in the previous reports dealing with this family of materials, which use costly annealings in closed silica tubes under controlled atmosphere, this new synthesis route enables the synthesis of pure phase materials at room temperature under air, with reasonable milling time. This synthesis procedure is easily scalable for large scale applications. - Highlights: • Phase pure BiCuSeO doped and undoped prepared by mechanical alloying. • Synthesis performed under air at room temperature. • Electrical properties similar to that of samples synthesized by a classical path.},
doi = {10.1016/J.JSSC.2013.04.029},
url = {https://www.osti.gov/biblio/22309035}, journal = {Journal of Solid State Chemistry},
issn = {0022-4596},
number = ,
volume = 203,
place = {United States},
year = {Mon Jul 15 00:00:00 EDT 2013},
month = {Mon Jul 15 00:00:00 EDT 2013}
}