Direct synthesis of BiCuChO-type oxychalcogenides by mechanical alloying
Abstract
We report on the direct synthesis of BiCuChO based materials by mechanical alloying (Ch=Se, Te). We show that contrary to the synthesis paths used in the previous reports dealing with this family of materials, which use costly annealings in closed silica tubes under controlled atmosphere, this new synthesis route enables the synthesis of pure phase materials at room temperature under air, with reasonable milling time. This synthesis procedure is easily scalable for large scale applications. - Highlights: • Phase pure BiCuSeO doped and undoped prepared by mechanical alloying. • Synthesis performed under air at room temperature. • Electrical properties similar to that of samples synthesized by a classical path.
- Authors:
-
- Institut de Chimie Moléculaire et des Matériaux d’Orsay, Univ. Paris-Sud, UMR 8182, Orsay F-91405 (France)
- France
- Publication Date:
- OSTI Identifier:
- 22309035
- Resource Type:
- Journal Article
- Journal Name:
- Journal of Solid State Chemistry
- Additional Journal Information:
- Journal Volume: 203; Other Information: Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0022-4596
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ANNEALING; CONTROLLED ATMOSPHERES; DOPED MATERIALS; ELECTRICAL PROPERTIES; SILICA; SYNTHESIS
Citation Formats
Pele, Vincent, Barreteau, Celine, CNRS, Orsay F-91405, Berardan, David, CNRS, Orsay F-91405, Zhao, Lidong, Dragoe, Nita, and CNRS, Orsay F-91405. Direct synthesis of BiCuChO-type oxychalcogenides by mechanical alloying. United States: N. p., 2013.
Web. doi:10.1016/J.JSSC.2013.04.029.
Pele, Vincent, Barreteau, Celine, CNRS, Orsay F-91405, Berardan, David, CNRS, Orsay F-91405, Zhao, Lidong, Dragoe, Nita, & CNRS, Orsay F-91405. Direct synthesis of BiCuChO-type oxychalcogenides by mechanical alloying. United States. https://doi.org/10.1016/J.JSSC.2013.04.029
Pele, Vincent, Barreteau, Celine, CNRS, Orsay F-91405, Berardan, David, CNRS, Orsay F-91405, Zhao, Lidong, Dragoe, Nita, and CNRS, Orsay F-91405. 2013.
"Direct synthesis of BiCuChO-type oxychalcogenides by mechanical alloying". United States. https://doi.org/10.1016/J.JSSC.2013.04.029.
@article{osti_22309035,
title = {Direct synthesis of BiCuChO-type oxychalcogenides by mechanical alloying},
author = {Pele, Vincent and Barreteau, Celine and CNRS, Orsay F-91405 and Berardan, David and CNRS, Orsay F-91405 and Zhao, Lidong and Dragoe, Nita and CNRS, Orsay F-91405},
abstractNote = {We report on the direct synthesis of BiCuChO based materials by mechanical alloying (Ch=Se, Te). We show that contrary to the synthesis paths used in the previous reports dealing with this family of materials, which use costly annealings in closed silica tubes under controlled atmosphere, this new synthesis route enables the synthesis of pure phase materials at room temperature under air, with reasonable milling time. This synthesis procedure is easily scalable for large scale applications. - Highlights: • Phase pure BiCuSeO doped and undoped prepared by mechanical alloying. • Synthesis performed under air at room temperature. • Electrical properties similar to that of samples synthesized by a classical path.},
doi = {10.1016/J.JSSC.2013.04.029},
url = {https://www.osti.gov/biblio/22309035},
journal = {Journal of Solid State Chemistry},
issn = {0022-4596},
number = ,
volume = 203,
place = {United States},
year = {Mon Jul 15 00:00:00 EDT 2013},
month = {Mon Jul 15 00:00:00 EDT 2013}
}
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