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Title: Anharmonic effects in the thermoelectric properties of PbTe

Journal Article · · Journal of Applied Physics
DOI:https://doi.org/10.1063/1.4891201· OSTI ID:22308529
;  [1]
  1. School of Physics, University of Exeter, Stocker Road, Exeter EX4 4QL (United Kingdom)

In this work, we investigate the crystal anharmonic effects in the thermoelectric properties of n-type PbTe. The lattice thermal transport coefficient is computed by employing an isotropic continuum model for the dispersion relation for acoustic as well as optical phonon branches, an isotropic continuum model for crystal anharmonicity, and the single-mode relaxation time scheme. The electronic components of the transport coefficients in a wide temperature range are calculated using the isotropic-nearly-free-electron model, interaction of electrons with deformation potential of acoustic phonons, and the effect of the band non-parabolicity. It is found that the transverse optical branches play a major role in determining the phonon conductivity and the thermoelectric figure of merit of this material.

OSTI ID:
22308529
Journal Information:
Journal of Applied Physics, Vol. 116, Issue 4; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); ISSN 0021-8979
Country of Publication:
United States
Language:
English