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Title: Spectroscopic studies on two mono nuclear iron (III) complexes derived from a schiff base and an azodye

Two new mono nuclear Fe(III) complexes of an azodye (ANSN) and a Schiff base (FAHP) are reported. The azodye is prepared by coupling diazotized 1-amino-2-naphthol-4-sulphonicacid with 2-naphthol and the Schiff base is prepared by condensing 2-amino-3-hydroxy pyridine with furfural. The complexes were synthesized by the reaction of FeCl{sub 3}Ðœ‡2H{sub 2}O with respective ligands. They were characterized on the basis of elemental analysis and spectral studies like IR, NMR, Electronic and M.ssbauer. Magnetic susceptibility and Molar conductance of complexes at room temperature were studied. Based on the spectroscopic evidences and other analytical data the complexes are formulated as[Fe(ANSN)Cl(H{sub 2}O){sub 2}] and [Fe(FAHP)Cl{sub 2}(H{sub 2}O){sub 2}].
Authors:
;  [1] ; ;  [2]
  1. University College, M G Road, Palayam, Thiruvananthapuram 695 034 Kerala (India)
  2. Solid State Physics Division, Bhabha Atomic Research Centre, Mumbai 400 085 (India)
Publication Date:
OSTI Identifier:
22308013
Resource Type:
Journal Article
Resource Relation:
Journal Name: AIP Conference Proceedings; Journal Volume: 1620; Journal Issue: 1; Conference: Optics 14: International conference on optics: Light and its interactions with matter, Calicut, Kerala (India), 19-21 Mar 2014; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; ABSORPTION SPECTROSCOPY; CHLORINE; FURFURAL; INFRARED SPECTRA; IRON CHLORIDES; IRON COMPLEXES; LIGANDS; MAGNETIC SUSCEPTIBILITY; MOESSBAUER EFFECT; NMR SPECTRA; NUCLEAR MAGNETIC RESONANCE; PYRIDINE; SCHIFF BASES; TEMPERATURE RANGE 0273-0400 K; WATER