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Title: Digital model for X-ray diffraction with application to composition and strain determination in strained InAs/GaSb superlattices

We propose a digital model for high quality superlattices by including fluctuations in the superlattice periods. The composition and strain profiles are assumed to be coherent and persist throughout the superlattice. Using this model, we have significantly improved the fit with experimental X-ray diffraction data recorded from the nominal InAs/GaSb superlattice. The lattice spacing of individual layers inside the superlattice and the extent of interfacial intermixing are refined by including both (002) and (004) and their satellite peaks in the fitting. For the InAs/GaSb strained layer superlattice, results show: (i) the GaSb-on-InAs interface is chemically sharper than the InAs-on-GaSb interface, (ii) the GaSb layers experience compressive strain with In incorporation, (iii) there are interfacial strain associated with InSb-like bonds in GaSb and GaAs-like bonds in InAs, (iv) Sb substitutes a significant amount of In inside InAs layer near the InAs-on-GaSb interface. For support, we show that the composition profiles determined by X-ray diffraction are in good agreement with those obtained from atom probe tomography measurement. Comparison with the kinetic growth model shows a good agreement in terms of the composition profiles of anions, while the kinetic model underestimates the intermixing of cations.
Authors:
; ;  [1] ;  [2] ;  [3] ; ;  [4] ;  [5]
  1. Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801 (United States)
  2. (United States)
  3. CEA/INAC/SP2M/LEMMA, 19 rue des Martyrs, 38054 Grenoble (France)
  4. Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208 (United States)
  5. (NUCAPT), Northwestern University, Evanston, Illinois 60208 (United States)
Publication Date:
OSTI Identifier:
22306165
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Applied Physics; Journal Volume: 116; Journal Issue: 1; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; ANIONS; CATIONS; COMPUTERIZED SIMULATION; CRYSTAL GROWTH; FLUCTUATIONS; GALLIUM ANTIMONIDES; GALLIUM ARSENIDES; INDIUM ANTIMONIDES; INDIUM ARSENIDES; INTERFACES; LAYERS; STRAINS; SUPERLATTICES; TOMOGRAPHY; X-RAY DIFFRACTION